Use of Non GAAP Measures Page 3 -150.00% -100.00% -50.00% 0.00% 50.00% 100.00% 150.00% 200.00% 250.00% 300.00% 350.00% PolyOne S&P 500 Strategy and Execution Drive Results – Since 2006: Page 4 All time closing high of $26.63 May 28, 2013 • 14 consecutive quarters of double digit EPS growth • 380 basis point increase in return on sales • 300% share price expansion • 300% increase in total shareholder return • 42% CAGR EPS expansion • $1.8 billion increase in market cap • Track record of successful acquisitions The World’s Premier Provider of Specialized Polymer Materials, Services & Solutions Four Pillar Strategy Page 5 2013 Portfolio Transformation Highlights • Substantial organic mix improvement drives 29% increase in first quarter EPS – 14th consecutive quarter of double-digit EPS growth • Completed acquisition of Spartech • Announced the creation of a new Specialty segment – Designed Structures and Solutions • Completed the sale of our non-core resin assets • Realigned our Specialty Coatings business into our GCAI segment Page 6 PP&S 15% Specialty Distribution 25% 0.12 0.27 0.21 0.13 0.68 0.82 1.00 2.50 $0.00 $0.25 $0.50 $0.75 $1.00 $1.25 $1.50 $1.75 $2.00 $2.25 $2.50 2006 2007 2008 2009 2010* 2011* 2012* 2015 Target Ad ju st ed E ar ni ng s P er S ha re Appliance 6% Building & Construction 13% Wire & Cable Electrical & Electronics 4% Consumer Packaging 18% Industrial 10% Misc. 5% HealthCare Transportation 16% Textiles 1% United States 70% Europe 14% Canada 8% Asia 5% Latin America 3% 2012 Revenues: $4.0 Billion* End Markets* 2012 Revenues: $4.0 Billion* EPS Page 7 * Pro Forma includes FY2012 results for Spartech (11/03/12 YE) and Glasforms & excludes discontinued operations PolyOne At A Glance * Restated to exclude discontinued operations Old PolyOne Transformation *Operating Income excludes corporate charges and special items **Pro Forma results include Spartech and Glasforms acquisitions, Specialty Coatings reclass and excludes resin assets 2% 34% 43% 45% 60% 65 – 75% 0% 20% 40% 60% 80% 100% 2005 2008 2010 2012 2012PF** 2015 % o f O pe ra tin g In co m e* JV's PP&S Distribution Specialty Specialty OI $5M $46M $87M $114M $150M Target Mix Shift Highlights Specialty Transformation 2015 Target Page 8 2007 Q1 2013 2015 Target 1) Operating Income % Specialty: Global Color, Additives & Inks 4.6% 11.7% 12 – 16% Global Specialty Engineered Materials 1.3% 10.1% 12 – 16% Designed Structures & Solutions -- 4.6% 8 – 10% Performance Products & Solutions 6.1% 8.1% 9 – 12% Distribution 3.0% 6.0% 6 – 7.5% 2) Specialty Platform % of Operating Income 20% 60% 65 – 75% 3) ROIC* (after-tax) 7% 9.2% 15% 4) Adjusted EPS Growth N/A 29% Double Digit Expansion Proof of Performance & 2015 Goals *ROIC is defined as TTM adjusted OI divided by the sum of average debt and equity over a 5 quarter period Page 9 *Percentage of Specialty Platform revenue from products introduced in last five years 19.5% 50.0% 2006 Q1 2013 $20.3 $41.9 2006 2012 14.3% 27.8% 2006 Q1 2013 Research & Development Spending Specialty Platform Vitality Index Progression* Innovation Drives Earnings Growth ($ millions) Specialty Platform Gross Margin % Page 10 We are Experts in Polymer Science and Formulation  Polymer Science  Formulation  Chemistry  Processing Inputs  Base Resins  Additives  Modifiers  Colorants Specialized Polymer Materials, Services, and Solutions Expertise Satisfied Consumers PolyOne Customer Innovative Products & Services  Marketplace Demands  Performance Requirements  Value Drivers Page 11 Positioned for Strong Growth 2015 Target Rev: $5B Adj. Strong past performance demonstrates that our strategy and execution are working • Megatrends align with our strengths • Innovation and services provide differentiation and competitive advantage • Strong and proven management team driving growth and performance • Addressable market exceeds $40 billion The New PolyOne: A Specialty Growth Company 2015 Target: $2.50 Adjusted EPS Page 16 Schedule I Reconciliation of Non-GAAP Financial Measures (Unaudited) (Dollars in millions, except per share data) Below is a reconciliation of non-GAAP financial measures to the most directly comparable measures calculated and presented in accordance with U.S. Average Debt Q1 2012 Q2 2012 Q3 2012 Q4 2012 Q1 2013 Average PolyOne Debt $ 706.4 $ 705.8 $ 705.2 $ 706.9 $ 1055.5 $ 776.0 Average Equity Q1 2012 Q2 2012 Q3 2012 Q4 2012 Q1 2013 Average PolyOne shareholders’ equity $ 611.3 $ 604.3 $ 629.3 $ 629.1 $ 871.8 $ 669.2 Platform sales and operating income (OI) 2012Y* 2012PF** Q1 2013 Global Specialty Engineered Materials Sales $ 543.6 $ 773.0 $ 159.8 Global Color, Additives and Inks Sales 703.5 828.5 205.3 Designed Structures & Solutions -- 850.6 41.5 Specialty Platform Sales $ 1,247.1 2,452.1 406.6 Performance Products and Solutions Sales 837.0 696.1 159.7 PolyOne Distribution Sales 1,030.3 1,030.3 268.0 Corporate and Eliminations (121.8) (121.6) (33.2) Total Sales $ 2,992.6 $ 4,056.9 $ 801.1 Global Specialty Engineered Materials OI $ 47.0 $ 47.7 $ 16.2 Global Color, Additives and Inks OI 66.8 81.6 24.1 Designed Structures & Solutions -- 20.9 1.9 Specialty Platform OI $ 113.8 $ 150.2 $ 42.2 Performance Products and Solutions OI 74.9 37.4 13.0 PolyOne Distribution OI 66.0 66.0 16.2 Corporate and eliminations (33.7) (40.0) (14.3) Special items in OI (53.9) (53.9) (16.6) Operating income - GAAP $ 167.1 $ 159.7 $ 40.5 Special items in OI 53.9 53.9 16.6 Operating income adjusted $ 221.0 $ 213.6 $ 57.1 Global Specialty Engineered Materials - OI % of sales 8.6% 6.1% 10.1% Global Color, Additives and Inks - OI % of sales 9.5% 9.8% 11.7% Designed Structures & Solutions -- 2.5% 4.6% Specialty platform OI % of sales 9.1% 6.1% 10.4% PP&S operating OI % of sales 9.0% 5.4% 8.1% Distribution OI % of sales 6.4% 6.4% 6.0% PolyOne OI adjusted, % of sales 7.4% 5.3% 7.1% PolyOne Investor Presentation�Credit Suisse Boston Basic Materials Conference ��June 26, 2013� Forward – Looking Statements Use of Non GAAP Measures Strategy and Execution Drive Results – Since 2006: Four Pillar Strategy 2013 Portfolio Transformation Highlights PolyOne�At A Glance Mix Shift Highlights Specialty Transformation Proof of Performance & 2015 Goals Innovation Drives Earnings Growth We are Experts in Polymer Science and Formulation Positioned for Strong Growth First Quarter Financial Highlights Debt Maturities & Liquidity Summary – 3/31/13 Use of Cash Why Invest In PolyOne?

Artisan™ AR7300 PRE-COLORED FORMULATIONS PROCESSING GUIDE Artisan™ Pre-Colored Thermoplastics Artisan™ AR7300 pre-colored thermoplastics are customized ABS formulations to help manufacturers achieve brilliant and high-gloss metallic effect, excellent chemical resistance, and scratch resistance. Can cause issues with color variation, surface defects, loss of properties and may affect the weatherability.

Human Health & Safety Remafin™ Fiber Colorants for PP Discover our colorants for spun-dyed and spunbond polypropylene.

BEREA, Ohio – PolyOne ColorMatrix, a global leader in liquid color and additives for plastics,has launched the PlanetPak™ liquid delivery system, the latest in its line of eco-friendly packaging solutions, helping customers reach their environmental goals. Easy to transport, handle and store, this packaging system improves material handling safety while still efficiently delivering the high quality colorant stored within it. PolyOne Corporation, with 2013 revenues of $3.8 billion, is a premier provider of specialized polymer materials, services and solutions.

Excelite OnePager Grab Handle (2) TIER 1 MOLDER A U T O M O T I V E G R A B H A N D L E • Reduce production cycle times • Achieve processing consistency in chemical foaming additive (CFA) performance • Control dimensional stability and reduce production scrap rates • Lower conversion costs • Improved cycle time by 20% • Achieved additional 2% density reduction • Resulted in a finer cell structure with a higher cell density, significantly improving dispersion and dimensional stability • Maintained Class A finish • Reduced CFA use rate by 80% Excelite™ IM Chemical Foaming Additives KEY REQUIREMENTS* WHY AVIENT? https://www.avient.com/products/polymer-additives/foaming-agents/colormatrix-excelite-chemical-foaming-additives

PolyOne Expands Lineup of Pre-Certified Biocompatible Healthcare Colorants and Additives InVisiO™ Color Inspiration 2019+ Explores Color Strategies Rooted in Art and Design Evolution Game changing concentrates for polymer parts create a metallic surface finish that truly mimics paint while eliminating the painting process.

AVIENT ADVANCED COMPOSITES OVERVIEW LOWER ENERGY COSTS Requires less energy during installation and use INCREASE COMPETITIVE ADVANTAGE Customizable solutions for specific application needs REDUCE PRODUCT LIFECYCLE COSTS Lower installation time, as well as warranty and �part replacement � expenses EXTEND PRODUCT LIFETIME Corrosion, flame, fatigue and UV resistant for improved durability DESIGN STRONG, LIGHTER WEIGHT COMPONENTS Up to 75% lighter than steel and up to 25% lighter than aluminum ADVANCED COMPOSITES An exceptional alternative to traditional materials such as wood, ceramic and metal, advanced composite solutions enable designers to: • Design lighter weight structural components for increased lifetime performance and improved fuel efficiency—higher strength-to-weight ratios to exceed the structural performance of traditional materials while significantly reducing weight—up to 75% lighter than steel and up to 25% lighter than aluminum • Extend product lifetime to reduce part replacement and decrease warranty expenses— the corrosion, weather, flame and fatigue resistance of composite solutions improve component durability • Reduce product lifecycle costs—the extended product lifetime, along with the potential for reduced installation time and cost due to the lighter weight of composite solutions, significantly reduces the associated cost over the lifetime of a part • Lower energy costs—by leveraging a higher strength-to-weight ratio, composite solutions allow designers to engineer products that require less energy or power during installation and use • Increase competitive advantage—Avient advanced composite solutions can be customized to provide electrical insulation, thermal insulation, radiopacity, low thermal expansion, flexural memory and load damping, while delivering desired performance and aesthetic specifications TRANSPORTATION Truck floors, liners and aerodynamic components, rail car doors and panels, automotive structural solutions, leaf springs, traffic safety markers and delineators, air cargo unit load devices (ULDs) The Avient advanced composites portfolio offers customized solutions to serve a full range of markets and industries, including: USES & APPLICATIONS ENERGY Wind turbine blade stiffening components, sucker rods, oil & gas production solutions BUILDING & CONSTRUCTION Structural blast protection, garage doors, modular construction, temporary shelters, architectural columns, concrete and masonry reinforcements, pipe reinforcement HEALTHCARE External orthopedic fixators, endoscopy wands, prosthetics MARINE Panels for decking, bulkheads, cabinets, doors, transoms, ceilings; reinforcements for stringers; sail battens CONSUMER & RECREATION Archery bow limbs and risers, furniture springs, diving board springs, golf flagpoles, snowsports equipment, sporting stick shafts, paddle shafts, lightweight and extendable mast structures ELECTRICAL & TELECOMMUNICATIONS Utility poles and cross-arms, high voltage transmission & distribution insulator cores, surge arresters, bus bar covers and electrical tool components INDUSTRIAL Pallet stiffeners, pipe reinforcement, conveyor springs, dock shelters PROCESSES & CAPABILITIES Avient’s reinforced composite technologies use carbon, glass and aramid fibers with custom formulated thermoset or thermoplastic resins in continuous forming processes. These methods include: PULTRUSION • Fibers are impregnated with liquid thermoset resins, then pulled through a heated die to cure the resin and form the product • This continuous, automated manufacturing process creates constant cross section profiles of any pre-determined length with consistent, uniform quality and exceptional mechanical performance • Applications include rods and profiles of various lengths and complexities, such as utility poles, insulator core rods and structural beams CONTINUOUS FILAMENT WINDING • Combines the principles of filament winding with pultrusion to create constant or tapered cross- sectional tubing in precision sizes • The unique axial and biaxial fiber orientation provides flexural and tensile strength, as well as crush and burst resistance • Applications include lightweight shelter frames and sporting goods components CONTINUOUS RESIN TRANSFER MOLDING (CRTM™) • Engineered core materials are sandwiched between structural composite laminate face sheets • Continuous composite sandwich panels feature high specific strength and stiffness-to-weight ratio • Applications include ballistic resistant panels, truck floors and rail car doors CONTINUOUS FIBER REINFORCED THERMOPLASTICS • Fully recyclable tape, X-Ply™ (0°/90°), and other multi-ply configurations with widths up to 10' wide • Sandwich panels in unlimited lengths, up to 6" thick and 10' wide • High volume production capacity • Applications include structural and aerodynamic components in transportation, and reinforcement of materials such as wood and metal THERMOSET COMPOSITE LAMINATES & BARSTOCK • Unidirectionally reinforced barstock, laminates and hybrid composites engineered to maximize deflection and fatigue resistance • Customizable shapes and sizes • Applications include archery bow limbs, flat springs, prosthetics, sporting equipment THERMOSET FINISHING OPERATIONS • Customized finishing capabilities for barstock and laminates including machining, water-jet cutting, profiling/shaping, sanding, slitting, laminating, molding and coatings TESTING CAPABILITIES • Mechanical – Flexural, tensile, compression, shear, fatigue, impact resistance • Physical – Specific gravity/density, Barcol hardness, water absorption, void content, resin/fiber content, dye penetrant, viscosity • Thermomechanical – Coefficient of linear thermal expansion, glass transition temperature, deflection temperature, degree of cure, curing properties • Electrical – High-voltage, low current dry arc resistance of solid electrical insulation, dielectric strength, water diffusion ABOUT AVIENT ADVANCED COMPOSITES The Avient advanced composites portfolio consists of Glasforms™, Gordon Composites™ and Polystrand™ branded materials.

Resin impregnated fibers are chemically cured with thermal or ultraviolet energy to form a highly crosslinked thermoset matrix. This extruded polymer jacketing is available up to 17.0 mm. Low smoke, low halogen, flame rated and custom colors are also available for upjacketed composite rods.

Initial production will include specialty engineered polymer materials used in high performance applications that have the need for flame retardant properties, high strength and durability, stiffness, chemical resistance, or weatherability. in 2014 initially focused on the production of colorant and additives to serve end markets such as transportation, electronics & electrical, healthcare, wire & cable, and packaging.  is a premier provider of specialized polymer materials, services and solutions.

 (NYSE: POL), a premier global provider of specialized polymer materials, services and solutions, today announced the acquisition of Magenta Master Fibers (Magenta), an innovative developer of specialty solid color concentrates for the global fiber industry.  president, Global Color, Additives and Inks,  is a premier provider of specialized polymer materials, services and solutions.