OUR CULTURE Core Values Collaboration. These core values, which begin with our individual decisions and actions, focus our attention on putting the customer first by creating genuine value through collaboration, innovation and an unwavering commitment to excellence.

S&P 500 -150% -50% 50% 150% 250% 350% 450% 550% POL S&P 500 All time high of $43.34 July 1st, 2014 PolyOne Corporation Page 9 2006 2014 YTD 2015 “Where we were” “Where we are” Target 1) Operating Income % Specialty: Global Color, Additives & Inks 1.7% 14.9% 12 – 16% Global Specialty Engineered Materials 1.1% 12.1% 12 – 16% Designed Structures & Solutions -- 7.6% 8 – 10% Performance Products & Solutions 5.5% 8.1% 9 – 12% Distribution 2.6% 6.2% 6 – 7.5% 2) Specialty Platform % of Operating Income 6.0% 65% 65 – 75% 3) ROIC* 5.0% 10.6% 15% 4) Adjusted EPS Growth N/A 37% Double Digit Expansion Proof of Performance & 2015 Goals *ROIC is defined as TTM adjusted OI divided by the sum of average debt and equity over a 5 quarter period PolyOne Corporation Page 10 32% Adjusted EPS CAGR from 2011 2015 EPS: $2.50 2011 EPS: $0.82 Continued Gross Margin Expansion Mergers & Acquisitions Spartech Accretion Incremental Share Buybacks Ongoing LSS Programs (50-100 bps/yr) Accelerated Innovation & Mix Improvement Several Levers to Drive Growth Mid Single Digit Revenue Growth PolyOne Corporation Page 11 Innovation Drives Earnings Growth *Percentage of Specialty Platform revenue from products introduced in last five years $20 $53 2006 2013 Research & Development Spending ($ millions) Specialty Platform Vitality Index Progression* 14% 31% 2006 2013 Specialty Platform Gross Margin % 20% 43% 2006 2013 Specialty Vitality Index Target ≥ 35% Vitality Products + 700 to 1000 bps PolyOne Corporation Page 12 Prototype Frame Opportunity Scale-up & Test Market Build Business Case Commercial Launch Phase 1 Phase 2 Phase 3 Phase 4 Phase 5 4 11 5 10 6 9 3 4 2 15 9 1 10 4 Breakthrough Platform Derivative A Rich Pipeline of Opportunity Number of Projects 25 14 19 17 18 93 Addressable Market ($ millions) TBD TBD $800 $450 $450 $1,700 PolyOne Corporation Page 13 Megatrends Aligned with Key End Markets Decreasing Dependence on Fossil Fuels Protecting the Environment Improving Health and Wellness Megatrend End Markets Globalizing and Localizing Health & Wellness Transportation Packaging Consumer PolyOne Corporation Page 14 60% 100% 20% 30% 40% 50% 60% 70% 80% 90% 100% 2008 2014 Pension Funding** As of September 30, 2014 Debt Maturities & Pension Funding – 9/30/14 Net Debt / EBITDA* = 1.7x $48 $317 $600 $0 $100 $200 $300 $400 $500 $600 $700 $800 2015 2020 2023 Debt Maturities As of September 30, 2014 ($ millions) Coupon Rates: 7.500% 7.375% 5.250% ** includes US-qualified pension plans only *TTM 9/30/2014 PolyOne Corporation Page 15 Free Cash Flow and Strong Balance Sheet Fund Investment / Shareholder Return Expanding our sales, marketing, and technical capabilities Targets that expand our: • Specialty offerings • End market presence • Geographic footprint • Operating Margin Synergy opportunities Adjacent material solutions Repurchased 1.5 million shares in Q3 2014 Repurchased 9.7 million shares since early 2013  10.3 million shares are available for repurchase under the current authorization Organic Growth Acquisitions Share Repurchases Dividends  Investing in operational and LSS initiatives (including synergy capture) Manufacturing alignment $0.16 $0.20 $0.24 $0.32 $0.40 $0.10 $0.20 $0.30 $0.40 $0.50 2011 2012 2013 2014 2015 Annual Dividend PolyOne Corporation Page 16 PolyOne Core Values Innovation Collaboration Excellence PolyOne Corporation Page 17 The New PolyOne: A Specialty Growth Company Why Invest In PolyOne? ��PolyOne Investor Presentation�Bank of America Merrill Lynch �2014 US Basic Materials Conference�Boston, MA�December 11, 2014�� Forward-Looking Statements Use of Non-GAAP Measures PolyOne Commodity to Specialty Transformation PolyOne�At A Glance Mix Shift Highlights Specialty Transformation Confirmation of Our Strategy Strategy and Execution Drive Results Proof of Performance & 2015 Goals 32% Adjusted EPS CAGR from 2011 Innovation Drives Earnings Growth A Rich Pipeline of Opportunity Megatrends Aligned with Key End Markets Debt Maturities & Pension Funding – 9/30/14 Free Cash Flow and Strong Balance Sheet �Fund Investment / Shareholder Return PolyOne Core Values Why Invest In PolyOne?

S&P 500 All time high of $43.34 July 1st, 2014 PolyOne Corporation Page 8 2006 2014 YTD 2015 “Where we were” “Where we are” Target 1) Operating Income % Specialty: Global Color, Additives & Inks 1.7% 15.2% 12 – 16% Global Specialty Engineered Materials 1.1% 11.8% 12 – 16% Designed Structures & Solutions -- 7.1% 8 – 10% Performance Products & Solutions 5.5% 8.0% 9 – 12% Distribution 2.6% 6.0% 6 – 7.5% 2) Specialty Platform % of Operating Income 6.0% 66% 65 – 75% 3) ROIC* 5.0% 9.9% 15% 4) Adjusted EPS Growth N/A 40% Double Digit Expansion Proof of Performance & 2015 Goals *ROIC is defined as TTM adjusted OI divided by the sum of average debt and equity over a 5 quarter period (Est. in 2012) PolyOne Corporation Page 9 Bridge to $2.50 Adjusted EPS by 2015 2015 EPS: $2.50 2013 EPS: $1.31 Continued Gross Margin Expansion Mergers & Acquisitions Spartech Accretion Incremental Share Buybacks Ongoing LSS Programs (50-100 bps/yr) Accelerated Innovation & Mix Improvement Several Levers to Drive Growth Mid Single Digit Revenue CAGR PolyOne Corporation Page 10 Innovation Drives Earnings Growth *Percentage of Specialty Platform revenue from products introduced in last five years $20 $53 2006 2013 Research & Development Spending ($ millions) Specialty Platform Vitality Index Progression* 14.3% 30.7% 2006 2013 Specialty Platform Gross Margin % 19.5% 43.0% 2006 2013 Specialty Vitality Index Target ≥ 35% PolyOne Corporation Page 11 Prototype Frame Opportunity Scale-up & Test Market Build Business Case Commercial Launch Phase 1 Phase 2 Phase 3 Phase 4 Phase 5 4 11 5 10 6 9 3 4 2 15 9 1 10 4 Breakthrough Platform Derivative A Rich Pipeline of Opportunity* Number of Projects 25 14 19 17 18 93 Addressable Market ($ millions) TBD TBD $800 $450 $450 $1,700 *Pipeline as of May 29, 2014 as presented during our Innovation Day PolyOne Corporation Page 12 Healthcare Consumer Packaging and Additive Technology Transportation Unique and Innovative Solutions https://www.dropbox.com/sh/dwe4t8aacvhb8ui/uD3p_bdglP/Presentation revise pics/GLS Beverage can closure XO 2.jpg https://www.dropbox.com/sh/dwe4t8aacvhb8ui/-YgkycKypw/Anti-Counterfeiting release & images/GN1979.JPG PolyOne Corporation Page 13 Megatrends Aligned with Key End Markets Decreasing Dependence on Fossil Fuels Protecting the Environment Improving Health and Wellness Megatrend End Markets Globalizing and Localizing Health & Wellness Transportation Packaging Consumer PolyOne Corporation Page 14 60% 100% 20% 30% 40% 50% 60% 70% 80% 90% 100% 2008 2014 Pension Funding** As of June 30, 2014 Debt Maturities & Pension Funding – 6/30/14 Net Debt / EBITDA* = 1.8x $48 $317 $600 $0 $100 $200 $300 $400 $500 $600 $700 $800 2015 2020 2023 Debt Maturities As of June 30, 2014 ($ millions) Coupon Rates: 7.500% 7.375% 5.250% ** includes US-qualified pension plans only *TTM 6/30/2014 PolyOne Corporation Page 15 Free Cash Flow and Strong Balance Sheet Fund Investment / Shareholder Return $0.16 $0.20 $0.24 $0.32 $0.10 $0.20 $0.30 $0.40 2011 2012 2013 2014 Annual Dividend Expanding our sales, marketing, and technical capabilities Targets that expand our: • Specialty offerings • End market presence • Geographic footprint • Operating Margin Synergy opportunities Adjacent material solutions Repurchased 1.8 million shares in Q2 2014 Repurchased 8.2 million shares since early 2013  11.8 million shares are available for repurchase under the current authorization Organic Growth Acquisitions Share Repurchases Dividends  Investing in operational and LSS initiatives (including synergy capture) Manufacturing alignment PolyOne Corporation Page 16 PolyOne Core Values Innovation Collaboration Excellence PolyOne Corporation Page 17 The New PolyOne: A Specialty Growth Company Why Invest In PolyOne? ��PolyOne Investor Presentation�Jefferies 2014 Global Industrials Conference�New York, NY�August 12, 2014�� Forward-Looking Statements Use of Non-GAAP Measures PolyOne Commodity to Specialty Transformation PolyOne�At A Glance Mix Shift Highlights Specialty Transformation Confirmation of Our Strategy Strategy and Execution Drive Results Proof of Performance & 2015 Goals Bridge to $2.50 Adjusted EPS by 2015 Innovation Drives Earnings Growth A Rich Pipeline of Opportunity* Unique and Innovative Solutions Megatrends Aligned with Key End Markets Debt Maturities & Pension Funding – 6/30/14 Free Cash Flow and Strong Balance Sheet �Fund Investment / Shareholder Return PolyOne Core Values Why Invest In PolyOne?

At PDI, our goals are to help clients: • Solve the toughest technical problems • Grow their business • Commercialize products quickly Core Competencies We offer unmatched expertise in material, process, and end product polymer testing, including: • Support studies for device qualifi cation • Material analysis and identifi cation • Suggestions on process improvement • Advanced failure analysis • Litigation support The PDI Difference We provide solutions—not just raw data We help you determine the root cause of failure and recommend real-world solutions and better routes to successful commercialization. At PDI, our goals are to help clients: • Solve the toughest technical problems • Grow their business • Commercialize products quickly Core Competencies We offer unmatched expertise in material, process, and end product polymer testing, including: • Support studies for device qualifi cation • Material analysis and identifi cation • Suggestions on process improvement • Advanced failure analysis • Litigation support The PDI Difference We provide solutions—not just raw data We help you determine the root cause of failure and recommend real-world solutions and better routes to successful commercialization.

Avient Advanced Composites – Polystrand 8375 Highfield Parkway Englewood, CO 80112 303.515.7700 TESTING SERVICES In-house testing capabilities allow for rapid material characterization and mechanical analysis according to the following standards: • ASTM D790 3-Point Flex • ASTM D7264 4-Point Flex • ASTM D2344 Short Beam Shear • ASTM C393 Core Compression • ASTM D7078 V-Notch Shear • ASTM D7249 4-Point Flex (Long Beam) • ASTM D6641 CLC Compression For more specialized resin and material analysis, additional testing capabilities are available through Polymer Diagnostics, Inc.

Key Features • Good chemical resistance • Hydrophobic • Good abrasion resistance • Good tensile strength Disadvantages • Flammable • Dissolves in strong alkalis • Susceptible to creep FIBER-LINE® PROCESS FOR PET POLYESTER • Coating • Twisting • Extrusion • Precision Winding FIBER-LINE® PET POLYESTER PRODUCTS • Swellcoat® Binder Yarn • Swellcoat® Buffer Thread • Swellcoat® Filler Yarn • Ripcords • Round Sling Core Yarn Abrasion Resistance Yarn on Yarn Abrasion Ultraviolet (UV) Resistance Flame Resistance Chemical Resistance (Acid) Chemical Resistance (Alkali) Chemical Resistance (Organic Solvent) P P P X P O P Property UOM Value Breaking Tenacity g/d 9.3 Specific Gravity Ratio 1.38 Elongation @ Break % 14.6 Tensile Modulus g/d 120 Moisture Regain* % 0.4 Creep** % 1.0 – 12.0 Shrinkage*** % 8.0 – 15.0 Melt Point °C 256 Decomposition Temp.

Proprietary composite formulations and technologies prevent voids and produce high-quality insulator core rods that withstand stringent electrical testing and end-use manufacturing stresses such as thermal overmolding and mechanical crimping.

MATERIAL SOLUTION DESCRIPTION KEY CHARACTERISTICS POTENTIAL APPLICATIONS Hammerhead™ FR Flame Retardant Composite Panels Industry-first flame retardant thermoplastic composite panels that meet ASTM E84 Class A standards for flame spread and smoke developed and configurations available to meet NFPA 286 corner room burn testing • Excellent flame performance • Moisture, UV, corrosion, impact, and rot resistant • Lightweight structural integrity • Reduce labor cost and time • Interior Wall, Floor & Ceiling Panel Systems • Garage Doors • Interior & Entry Doors • Exterior Sheathing • Siding & Cladding • Kitchen Cabinetry Hammerhead™ and Polystrand™ Composite Panels Thermoplastic composite panels constructed with Polystrand™ continuous fiber laminates thermally bonded to thermoplastic foam or honeycomb cores • Moisture, UV, corrosion, impact, and rot resistant • Lightweight structural integrity • Reduce labor cost and time • Garage Doors • Interior Entry Doors • Interior Wall, Floor & Ceiling Panel Systems • Exterior Sheathing • Siding & Cladding • Kitchen Cabinetry Polystrand™ Continuous Fiber Tapes & Laminates High strength unidirectional (UD) glass fibers combined with thermoplastic resins available in unidirectional tapes or multi-ply laminates • High strength and stiffness • Enables impact resistance • Formulations available to meet ASTM E84 Class A and Class B flame/smoke rating • Composite Deckng • Interior & Entry Doors • Roofing Systems GlasArmor™ Ballistic Resistant Panels Ballistic protection constructed from layers of 0°/90° woven E-glass fiber reinforcements with a proprietary thermoset resin system • UL 752 Level 1–3 compliant • Less than 25% the weight of comparable steel panel • 1-hr fire rating per ASTM E119* • Safe/Panic Rooms • Garage Doors • Interior & Entry Doors ThermoBallistic™ Thermoplastic Panels Industry-first thermoplastic ballistic resistant panels thermally formed with layers of 0°/90° UD E-glass fiber reinforcements and polyolefin-based resin systems • UL 752 Level 3 compliant • Extremely lightweight • Moisture, UV, and corrosion resistant • Safe/Panic Rooms • Garage Doors • Interior & Entry Doors * UL Level 3 panel was fire tested as part of a wall system with steel studs and drywall facesheet

and Kraton to focus on our core competencies and help our customers with new and unique solutions that differentiate them in the marketplace." Guided by its Core Values, Sustainability Promise and No Surprises PledgeSM,

With the sale of DSS, we can now entirely focus on accelerating growth in our four core segments. Guided by its Core Values, Sustainability Promise and No Surprises Pledge(SM),