https://www.avient.com/sites/default/files/resources/Overmolding_of_Thermoplastic_Elastomers_Engineered_solutions_for_consumer_product_differentiation.pdf
Figure 2.
Styrenic block copolymers 2.
Holden, “Application of Thermoplastic Elastomers”, 573, Thermoplastic Elastomers, 2nd edition, 1996 2.
https://www.avient.com/sites/default/files/2020-08/2020-composites-overmolding-overview.pdf
Mold to compress and cool into shape 4 CFRTP is preheated and inserted into tool 3 Material heating, melting, and conveying 2 Solid resin infeed 1 5 ON-ROAD TRANSPORTATION Underbody shields, underhood enclosures, interior components, storage OFF-ROAD VEHICLES Skid plates, doors, seat structures, exterior panels & moldings Traditionally, molding with short and long glass-filled polypropylene to gain flexural performance over unfilled polypropylene also results in a loss of impact resistance.
SPORTING GOODS Boots, bindings, protective equipment MARINE Hull reinforcement, seats, paddles 50% Long Glass Fiber Reinforced PP 50% Long Glass Fiber Reinforced PP + 0° CFRTP 50% Long Glass Fiber Reinforced PP + 0°/90° CFRTP 50% Long Glass Fiber Reinforced PP + 0°/90°/90°/0° CFRTP 17K 28K 29K 50% Long Glass Fiber Reinforced PP + 0°/90°/0° CFRTP 29K 31K +60.7% FLEXURAL STRENGTH (ASTM D7264) IMPACT RESISTANCE (ASTM D3763) 50% Long Glass Fiber Reinforced PP 50% Long Glass Fiber Reinforced PP + 0° CFRTP 50% Long Glass Fiber Reinforced PP + 0°/90° CFRTP 50% Long Glass Fiber Reinforced PP + 0°/90°/0° CFRTP 50% Long Glass Fiber Reinforced PP + 0°/90°/90°/0° CFRTP E ne rg y at T ot al ( J) Fo rc e at P ea k (k N ) 18 16 14 12 10 8 6 4 2 0 6.0 5.9 4.0 3.0 2.0 1.0 0.0 11.2 15.1 14.6 12.7 16.4 1.2 1.9 2.8 4.0 5.0 +58.3% +34.8% 50% Long Glass Fiber Reinforced PP 50% Long Glass Fiber Reinforced PP + 0° CFRTP 50% Long Glass Fiber Reinforced PP + 0°/90° CFRTP 50% Long Glass Fiber Reinforced PP + 0°/90°/90°/0° CFRTP 17K 28K 29K 50% Long Glass Fiber Reinforced PP + 0°/90°/0° CFRTP 29K 31K +60.7% FLEXURAL STRENGTH (ASTM D7264) IMPACT RESISTANCE (ASTM D3763) 50% Long Glass Fiber Reinforced PP 50% Long Glass Fiber Reinforced PP + 0° CFRTP 50% Long Glass Fiber Reinforced PP + 0°/90° CFRTP 50% Long Glass Fiber Reinforced PP + 0°/90°/0° CFRTP 50% Long Glass Fiber Reinforced PP + 0°/90°/90°/0° CFRTP E ne rg y at T ot al ( J) Fo rc e at P ea k (k N ) 18 16 14 12 10 8 6 4 2 0 6.0 5.9 4.0 3.0 2.0 1.0 0.0 11.2 15.1 14.6 12.7 16.4 1.2 1.9 2.8 4.0 5.0 +58.3% +34.8% Application design Modeling & simulation Prototyping & validation Material selection Composite/ resin compatibility Custom formulations Mold filling analysis Technical support Process optimization PROCESSING MATERIALS Material selection is crucial to an application’s success.
https://www.avient.com/sites/default/files/2021-01/eccoh-selection-guide-cn.pdf
特点 电线和电缆 高度阻燃 毒性和烟密度极低 不同级层间可交联 可与色母料、添加剂浓缩液、紫外稳定剂一同加工 高度阻燃 毒性和烟密度极低 适合进行挤压和注射成型 管和配件 材料(ECCOH) 5924C 5920 5511C 5806UV 5127UV 5549/1 8300-8001 8300-8003 8300-8008 1125C 1052C 5309 5995/1C 5555C 5286 3140-3 6151 5865C XLS8002 6649 中低压电缆 光缆 机车/船 光缆 电缆/光缆 电子线 电缆 电子线 电子线 电缆 机车缆护套 电缆/光缆 电缆 机车缆 电缆 电缆/光缆 电缆 电缆 电缆/光缆 应用 热老化等级 热塑性 √ √ √ √交联型 交联方式 密度48 熔融指数(150℃/21.6kg) 硬度shore D 拉伸强度MPa 断裂伸长率% 氧指数% 耐环境应力开裂ESCR 阻燃性能 低温性能 耐油性能 耐UV性能 耐泥浆性能 低摩擦性能 产地 有焰(1mm)ASTM E662 无焰(1mm) 70 235 C类 √ √ √ 中国 45 265 中国 68 275 √ √ √ 欧洲 210 √ C类 中国 1.49~1.51 4.0 54 12.5 200 36 1.47 3.5 55 14 210 34 1.53 0.8 56 14 150 40 1.51 1 47 9.5 170 38 1.46 3.8 54 15.5 180 32 √ 中国 1.6 2.9 49 11.7 170 45 CPR B √ √ 中国/欧洲 1.29 13.5 48 17.5 345 27 FT-2 中国 1.27 9.5 48 13 360 29 90 190 √ 中国 1.49 8 53 15.7 245 35 63 180 √ 中国 1.54 2.7 55 11.5 180 40 106 214 CPR C √ √ 中国 1.5 8 50 12.5 180 34 84 206 C类 √ 中国 1.5 1.6 46 14 250 39 √ √ √ 欧洲 1.48 3 46 11 215 36 √ √ 欧洲 1.6 2.8 48 10.3 165 41 √ √ √ 欧洲 1.58 4.2 48 12.4 160 46 CPR B √ 欧洲 1.46 6 53 17 160 33 39 143 √ 欧洲 1.51 4 53 11.5 170 43 50 150 √ √ √ 中国 1.54 2.3 56 11.5 155 35 D类 中国 1.5 5.8 12 250 27 FT-2 中国 1.35 10 49 15 320 28 FT-2 中国 辐照/硅烷 辐照 辐照 辐照 辐照 辐照 自交联/水浴辐照/硅烷 √ √ √ √ √ √ √ √ √ √ √ √ √ √ √ √ 90℃ 90℃ 90℃ 105℃ 90℃ 105℃ 125℃ 105℃ 105℃ 105℃ 90℃ 90℃ 90℃105℃ 105℃ 105℃ 105℃ 105℃ 加工方式(挤出) 材料性能:热塑状态(非交联后) 烟密度(最大) 特殊性能 ECCOH™低烟、无卤解决方案
https://www.avient.com/sites/default/files/2020-09/surround-processing-guide-2020.pdf
TEMPERATURE Material Rear °F (°C) Center °F (°C) Front °F (°C) Nozzle °F (°C) Melt °F (°C) Mold °F (°C) Nylon 6,6 14% NiCF 540–570 (280–300) 530–560 (275–290) 530–560 (275–290) 540–570 (280–300) 540–570 (280–300) 200–300 (90–150) Nylon 6,6 30% SS 540–570 (280–300) 530–560 (275–290) 530–560 (275–290) 540–570 (280–300) 540–570 (280–300) 200–300 (90–150) PBT 14% NiCF 510–410 (265–280) 490–540 (255–280) 480–530 (250–275) 480–530 (250–275) 480–530 (250–275) 150–250 (65–120) PC 14% NiCF 540–570 (280–300) 540–570 (280–300) 530–560 (275–290) 530–560 (275–290) 530–560 (275–290) 150–250 (65–120) ABS 14% NiCF 470–520 (240–270) 460–520 (240–270) 460–520 (240–270) 460–530 (240–275) 460–530 (240–275) 100–200 (40–90) PP 14% NiCF 440–480 (225–250) 440–480 (225–250) 430–470 (220–245) 420–460 (215–240) 420–460 (215–240) 125–175 (50–80) DRYING Material Temperature °F (°C) Time Minimum Moisture Maximum Moisture Nylon 6,6 14% NiCF 180 (80) 4–5 hours 0.05% 0.20% Nylon 6,6 30% SS 180 (80) 4–5 hours 0.05% 0.20% PBT 14% NiCF 250 (120) 6-8 hours 0.02% 0.03% PC 14% NiCF 250 (120) 3–4 hours 0.02% 0.02% ABS 14% NiCF 200 (90) 2–4 hours 0.05% 0.10% PP 14% NiCF 180 (80) 2–4 hours 0.20% 0.30% Equipment • Feed throats smaller than 2.5" may cause bridging due to pellet size - Larger feed throats will be more advantageous with long fiber EMI shielding resins • General purpose metering screw is recommended - Mixing/barrier screws are not recommended • L/D ratio - 18:1–20:1 (40% feed, 40% transition, 20% metering) • Low compression ratio - 2:1–3:1 • Deep flights recommended - Metering zone 3.5 mm - Feed zone 7.5 mm • Check ring - Three-piece, free-flowing check ring • General purpose nozzle (large nozzle tips are recommended) - Minimum orifice diameter of 7/32" - Tapered nozzles are not recommended for long fiber EMI shielding resins • Clamp tonnage: - 2.5–5 tons/in2 Gates • Large, free-flow gating recommended - 0.25" x 0.125" land length - 0.5" gate depth Runners • Full round gate design • No sharp corners • Minimum of 0.25" diameter • Hot runners can be used PROCESSING Screw Speed Slower screw speeds are recommended to protect fiber length Back Pressure Lower back pressure is recommended to protect fiber length Pack Pressure 60–80% of max injection pressure Hold Pressure 40–60% of max injection pressure Cool Time 10–30 seconds (depends on part geometry and dimensional stability) PROCESS CONSIDERATIONS Recommended – retain fiber length (maximize conductivity) • Low shear process • Low screw speed and screw RPM • Slow Injection speed • Fill to 99–100% on first stage of injection - Reduces potential nesting of fibers at gate location - Improves mechanical performance near gate location - Promotes ideal fiber orientation Resin Rich Surface • Achieved when using a hot mold temperature and longer cure times ≥ Max mold temperature recommendation • Improved surface aesthetic • Reduced surface conductivity • Could reduce attenuation performance in an assembly Fiber Rich Surface • Achieved when using a cold mold temperature and shorter cure times ≤ Minimum mold temperature recommendation • Improved surface aesthetic • Reduced surface conductivity • Could improve attenuation performance in an assembly www.avient.com Copyright © 2020, Avient Corporation.
https://www.avient.com/products/polymer-colorants/solid-color-masterbatches/oncolor-ul-94-colorants
V-0, V-1, V-2 and 5VA/5VB ratings for more than 200 specific engineering resins
https://www.avient.com/news/avient-introduces-versaflex-tf-adhesive-tpes-textile-fabrics
All Versaflex TF Adhesive TPEs comply with the OEKO-TEX(R) 100-2 standard, do not include plasticizers, and contain lower VOCs than traditional adhesive solutions.
https://www.avient.com/news/extreme-conditions-are-no-match-new-outdoor-sign-material
December 2, 2015
https://www.avient.com/news/pet-friendly-soft-touch-design-delivers-remarkable-fundraising-dog-toy
July 2, 2015
https://www.avient.com/news/new-polyone-technology-improves-brand-protection-and-combats-counterfeiting-consumer-electronics
September 2, 2014
https://www.avient.com/news/explore-ballistic-panels-enhanced-security-solutions-avient-gsx-2024
They are available for protection up to UL 752 levels 1, 2, & 3 test standards for ballistic resistance.