Water Street North Baltimore, OH 45872 Activity: Design and Manufacture of Colour and Additive Concentrates, Activity: Design and Manufacture of Custom PVC Plastisol and PVC Slush Mold Powder Facility: Avient Corporation - Malmö, Sweden Järnyxegatan 7 P.O. WA-06, Kalyan-Padgha Road Vashere, Maharashtra 421302 Activity: Design and Manufacture of Colorants and Additives for Plastics Activity: Design & Manufacture of Color, Additive Concentrate & Specialty Facility: Avient Corporation - Suzano, Brasil Av. Jorge Bei Maluf, 2.165, Vila Theodoro Suzano, SP 08686-000 Brasil Facility: Avient Corporation - Suzhou, China 77 Shenggang Street Suzhou Industrial Park Suzhou, Jiangsu Province 215024 Activity: Design and Manufacture of Colorants and Additives Concentrates Activity: Design and Manufacture of Plastics Compounding Material and Thermoplastic Elastomers Page 10 of 10 Facility: No.188 Quanzhou Road Suchu Industrial Park Chuzhou, Anhui Province 239000 Facility: Avient Corporation - Vonore, TN 245 Avecor Drive Vonore, TN 37885 Facility: Avient Corporation - Vonore Warehouse 225 Industrial Drive Vonore, TN 37885 Activity: Manufacture of Colorants and Additives for Plastics Activity: Warehouse

They are based on management’s expectations that involve a number of business risks and uncertainties, any of which could cause actual results to differ materially from those expressed in or implied by the forward-looking statements.  A reconciliation of each non-GAAP financial measure with the most directly comparable GAAP financial measure is attached to this presentation which is posted on our website at www.polyone.com. 4 POLYONE CORPORATION What We Do Value Formulation Expertise Inputs Base resins Additives Modifiers Pigments Expertise in Polymer Materials, Services and Solutions OEMs Brand Owners Processers Assemblers Driving customer value with specialty products & services Service InVisiOSM Color Services IQ Design Labs LSS Customer First POLYONE CORPORATION 5 2016 Revenue ($3.3 Billion) by Segment At a Glance United States 65% Europe 12% Canada 8% Asia 8% Latin America 7% $0.13 $0.68 $0.82 $1.00 $1.31 $1.80 $1.96 $2.13 2009 2010 2011 2012 2013 2014 2015 2016 2016 Revenue by Geography 2016 Revenue by End Market Appliance 5% Building & Construction 11% Consumer 11% Electrical & Electronics 5% Healthcare 11% Industrial 15% Packaging 12% Textiles 2% Transportation 19% Wire & Cable 9% Adjusted Earnings Per Share Performance Products & Solutions 19% PolyOne Distribution 31% Designed Structures & Solutions 11% Specialty Engineered Materials 16% Color Additives and Inks 23% 6 POLYONE CORPORATION Returning Cash to Shareholders $0.16 $0.20 $0.24 $0.32 $0.40 $0.48 $0.54 $0.10 $0.20 $0.30 $0.40 $0.50 $0.60 2011 2012 2013 2014 2015 2016 2017 Annual Dividend*  Since 2011, we have returned nearly $850 million to shareholders  $150 million returned through dividends  $697 million returned through share repurchases $697M $0 $150 $300 $450 $600 $750 2011 2012 2013 2014 2015 2016 Cumulative Share Repurchases (in millions) *Initiated in 2011 7 POLYONE CORPORATION 2% 43% 79% 0% 20% 40% 60% 80% 100% 2005 2010 2016 % o f O pe ra tin g In co m e* *Operating Income excludes corporate charges and special items Specialty OI $5M $87M $273M Mix Shift Highlights Specialty Transformation Specialty = ROS > 10% JV’s Performance Products & Solutions Specialty Distribution 8 POLYONE CORPORATION 2006 2016 2020 “Where we were” “Where we are” Platinum Vision Operating Income % of Sales Color, Additives & Inks 1.7% 16.0% 20%+ Specialty Engineered Materials 1.1% 14.3% 20%+ Performance Products & Solutions 5.5% 11.1% 12 – 14% Distribution 2.6% 6.4% 6.5 – 7.5% Designed Structures & Solutions N/A -0.9% 8 – 10% ROIC* 5.0% 12.9% 15% Proof of Performance & 2020 Platinum Vision *ROIC is defined as TTM adjusted OI after tax divided by the sum of average debt and equity less cash over a 5 quarter period Consistently Deliver Double Digit Annual EPS Growth POLYONE CORPORATION 9 2,883 2,538 2006 2016 Volume (lbs in millions) -12% $103 $200 2006 2016 Commercial, R&D and Marketing Spending ($M) +95% $88 $317 2006 2016 Adjusted Operating Profit ($M) +263% Ours is Not a Cost Cutting Story 10 POLYONE CORPORATION Innovation Drives Earnings Growth *Specialty Platform revenue from products introduced in last five years $20 $54 2006 2016 Research & Development Spending ($ millions) Specialty Platform Vitality Index Progression* 14% 33% 2006 2016 CAI & SEM Gross Margin 12% 42% 2006 2016 Target ≥ 35% Innovation Pipeline Potential 11 POLYONE CORPORATION Primary Industries Served 2016 Revenue: $3.3 Billion Electrical & Electronic 5% Building & Construction 11% Appliance 5% Industrial 15% Wire & Cable 9% Healthcare 11% Consumer 11% Packaging 12% Transportation 19% Focus End Markets 12 POLYONE CORPORATION Therma-Tech™ & Sheet GEON™ Vinyl Polymer Colorants Therma-Tech™ TPE’s & Film TPE + OnForce™ Gravi-Tech™ Page 12 Film Target End Markets… Healthcare 13 POLYONE CORPORATION Sound & Vibration Management Fuel Handling Systems Interior & Exterior Trim Structural Braces & Brackets Interior Structural Components Lighting Air management Electronics & Cameras Fluid Handling Target End Markets… Automotive Underhood Components Roof Systems 14 POLYONE CORPORATION PreservaPak™ OnColor™ Smart Batch™ VersaFlex™ TPE Cap Liner ColorMatrix™ Amosorb™ Oxygen Scavenger ColorMatrix™ Ultimate™ UV Light Barrier OnCap™ Laser Marking Additives Target End Markets… Packaging 15 POLYONE CORPORATION Source: Outdoor Industry Association TPE Vibration Dampening (SEM/GLS) TPE + OnForce (SEM) OnForce (SEM) Advanced Composites (SEM) TPE Vibration Dampening (SEM/GLS) Thermoplastic Elastomers (SEM) Advanced Composites (SEM) Polymer Colorants (CAI) Sheet (DSS) TPE & Film (SEM + DSS) Advanced Composites (SEM) Polymer Colorants (CAI) Thermatech (SEM) Thermoplastic Elastomers (SEM) TPE + OnForce (SEM) OnForce (SEM) Target End Markets… Consumer 16 POLYONE CORPORATION Free Cash Flow and Strong Balance Sheet Fund Investment / Shareholder Return  Expanding our sales, marketing, and technical capabilities  Investing in operational and LSS initiatives  ~60 - 70% of capital expenditures fund growth initiatives Organic Growth Acquisitions Share Repurchases Dividends  Targets that expand our: • Specialty offerings • End market presence • Geographic breadth  Growth synergies  Adjacent material solutions  Repurchased 1.2 million shares in Q4 2016  Repurchased 18.8 million shares since early 2013  8.5 million shares are available for repurchase under the current authorization  Increased annual dividend by 12.5% to $0.54 per share, representing the sixth consecutive year of dividend growth POLYONE CORPORATION 17 The New PolyOne: A Specialty Growth Company Why Invest In PolyOne? Segment Highlights At a Glance: Color, Additives & Inks At a Glance: Specialty Engineered Materials At a Glance: Designed Structures & Solutions At a Glance: Performance Products & Solutions At a Glance: Distribution Application Examples Luxury Packaging�with Gravitech Density Modified Polymers Optimize Color Usage�with OnColor Super Concentrates Combat Bacteria Formation�with WithStand Antimicrobial Technology Medical Device Housings�with Chemically Resistant Engineered Polymers Color & Design Services Outdoor Applications Fiber Colorants�Solutions for clothing, apparel, footwear, automotive & sporting goods High-Barrier Packaging Containers Investor Presentation - January 2017 r14 Investor Presentation - January 2017

FlexCart metering units are designed with flexibility and functionality at the core of their design. THE DESIGN The basis of a PlanetPak is a robust polyethylene liner with a proprietary collapsing design, encompassed by a cardboard outer shell. Processing conditions can cause material properties to shift from the values stated in the information.

One major automotive supplier, however, questioned the norm when designing the interiors for a major automaker’s new vehicle model. THE SOLUTION The supplier’s design team approached Avient in hopes of finding an alternative material that could replace leather yet eliminate processing issues. Our design team created a formulation modified for the supplier’s specific processing environment.

When designing TPE parts, strive to keep the part wall thicknesses as uniform as possible and radius all sharp corners. LSR is a thermoset material. FLEXIBLE WEATHERABLE COLORABLE Selecting the right material for your application can have multiple nuances, from properties and processing to design and appearance.

P l O I t P t tiPolyOne Investor Presentation KeyBanc Capital Markets Basic Materials & Packaging Conference September 2016p PolyOne Corporation Page 1 Forward-Looking Statements  In this presentation, statements that are not reported financial results or other historical information are “forward-looking statements” within the meaning of the Private Securities Litigation Reform Act of 1995. They are based on management’s expectations that involve a number of business risks and uncertainties, any of which could cause actual results to differ materially from those expressed in or implied by the forward-looking statements. Q2 POL IR Presentation - 2016 KeyBanc Capital Markets Basic Materials & Packaging Conference Investor Presentation - September 14, 2016 r4 Investor Presentation - September 14, 2016

Processing conditions can cause material properties to shift from the values stated in the information. Processing conditions can cause material properties to shift from the values stated in the information. Both paperboard and multilayer polymers restrict design freedom, so the final packaging is often less than ergonomic.

There are a variety of Avient TPEs designed to have excellent adhesion to a number of rigid plastic substrates for overmolding. Versaflex™ OM 3060 – Silky clear solution designed for overmolding onto polycarbonate (PC), acrylonitrile butadiene styrene (ABS) and PC/ABS blends PC, ABS and PC/ABS overmolding materials are available in water-clear, natural, thin wall overmolding, and high performance grades.

As PET undergoes multiple remelting cycles, it can break down, suffering from thermal degradation, and resulting in a material of lower quality than its virgin counterpart. In addition, the importance of simulating the mechanical recycling process to design new additive technologies cannot be overstated. Designing additives and recycling processes with circularity in mind is essential for the future of sustainable plastic packaging.

As PET undergoes multiple remelting cycles, it can break down, suffering from thermal degradation, and resulting in a material of lower quality than its virgin counterpart. In addition, the importance of simulating the mechanical recycling process to design new additive technologies cannot be overstated. Designing additives and recycling processes with circularity in mind is essential for the future of sustainable plastic packaging.