of available liquidity." Liquidity is calculated as follows:  Liquidity

Wischodnia 6 Kutno 99-300 Poland Activity: Design and Manufacture of Color and Additive Concentrates and Activity: Design and Manufacture of Color and Additive Concentrates and Facility: Avient Corporation - Berea, OH 680 N. Rocky River Drive Berea, OH 44017 Facility: Avient Corporation - Assesse, Belgium (CAI & SEM) 2 Rue Melville Wilson Assesse 5330 Belgium Activity: Liquid Colorants and Additives for Plastics Activity: "Design of color concentrates, precolors, and compounds for fluoropolymer and high temperature polymers, LSFOH (low smoke and fume, zero halogen compounds), and Specialty Compounds Manufacture of Color and Additive Concentrates and Specialty Compounds" Page 6 of 7 Facility: Avient Corporation - Aland (Odkarby), Finland Kroklundsvagen 346 Ödkarby AX-22320 Finland Facility: Avient Corporation - Bethel, CT 19 Francis J Clark Circle Bethel, CT 06801 Activity: Manufacture of colorants and compounds for fluoropolymer and high temperature polymers Activity: Design and Manufacture of colorants and compounds for fluoropolymer and high temperature polymers. Ezcabarte calle H Nº3 Oricain, Navarra 31194 Facility: Avient Corporation - Tossiat, France 43 Place de la gare Tossiat 01250 France Activity: Design and Manufacture of Color and Additive Concentrates and Activity: Design and Manufacture of Color and Additive Concentrates and Page 7 of 7 Facility: Avient Corporation - Knowsley, United Kingdom Unity Grove Knowsley, Merseyside L349GT United Kingdom Facility: Avient Corporation - Alicante (Ibi - IQAP), Spain Guadalajara 6, Poligono Industrial L'Alfalç Ibi, Alicante 03440 Activity: Design and Manufacture of Liquid Colorants and Additives for Plastics, Assembly and Supply of Material Dosing Equipment Activity: Design, development and production of color concentrates and additives for plastic and synthetic fibers Facility: Avient Corporation - Vic (Barcelona), Spain Carretera de Vic a Olot,C-153, km 5 Masies de Roda, Barcelona 08500 Activity: Design, development and production of color concentrates and additives for plastic and synthetic fibers Facility: Avient Corporation - Melle, Germany Oldendorfer Straße 9 Thuringia 49342 Germany Facility: Avient Corporation - Gaggenau, Germany Adolf-Dambach-Str. 2 Gaggenau, Thuringia 76571 Germany Activity: Development and Manufacture of LSFOH (low smoke and fume, zero halogen) compounds Activity: Design and Manufacture of Specialty Engineered Thermoplastics

Industrial Valle del Cinca S/N Apartado E-22300 Barbastro Spain Berea, OH Liquid Colorants and Additives for Plastics , 680 N. Glendale - AZ 85307 United Grace-Hollogne, Belgium Warehousing and Dispatching of raw materials Rue Louis Bleriot 7 4460 Grace-Hollogne Belgium Gyor, Hungary Design and Manufacture of Color and Additive Concentrates and Specialty Compounds Mandulafa Sor 3 9027 Gyor Hungary Kennesaw, GA Design and manufacture of specialty inks and specialty coatings. , 8155 Cobb Center Drive Kennesaw - GA 30152 United Knowsley, United Kingdom Design and Manufacture of Liquid Colorants and Additives for Plastics, Assembly and Supply of Material Dosing Equipment , Unity Grove Knowsley - Merseyside L349GT United Kingdom Kutno, Poland Design and Manufacture of Color and Additive Concentrates and Specialty Compounds ul. The design and manufacture of Color & Additive Concentrates, Specialty Engineering Materials Plot No.

EPS: $1.00 $0.54 $0.68 $0.30 $0.45 $0.60 $0.75 H1'12 H1'13 Adjusted EPS $101.0 $132.6 $50.0 $100.0 $150.0 H1'12 H1'13 Adjusted Operating Income (millions) +31% $68.8 $97.7 $50.0 $75.0 $100.0 H1'12 H1'13 Specialty Operating Income (millions) First Half 2013 Financial Highlights • Adjusted EPS increased 26% over prior year first half • Operating Income expanded 31% versus first half 2012 • Specialty operating income up 42% • Revenue grew 22% versus 1H ‘12 • Portfolio transformation activities  Completed acquisition of Spartech  Divested non-core Resin business +26% +42% Page 12 • Significant Debt Maturities $ 1,010 Other Debt 21 • Total Debt at 6/30/13 Less: Cash Net Debt • Available Liquidity Cash ABL Availability Total Liquidity • Net Debt / EBITDA = 1.9x • Net Debt / EBITDA = 2.1x*(tax adjusted) $392 310 $702 $1,031 392 $639 $50 $360 $600 $0 $100 $200 $300 $400 $500 $600 $700 $800 2015 2020 2023 Significant Debt Maturities As of June 30, 2013 ($ millions) Page 13 Coupon Rates: 7.500% 7.375% 5.250% *Pro Forma TTM for taxes on resin gain Debt Maturities & Liquidity Summary – 6/30/13 Cash Balance = $392M Net Debt / EBITDA* = 1.9x • Repurchased ~3.0M shares YTD in 2013 • 17 million shares are available for repurchase under the current authorization Share Repurchase • Introduced a quarterly dividend in Q1 2011 and increased in Q1 2012 (25%) and Q1 2013 (20%) • Objective of maintaining and growing Dividends • Expanding our sales, marketing, and technical capabilities is top priority • Investing in operational and LSS initiatives (including synergy capture) • CAPEX Organic Growth • Targets that expand our: • Specialty offering • End market presence • Geographic footprint • Synergy opportunities • Adjacent material solutions • North American manufacturing alignment Acquisitions *TTM 6/30/2013 Use of Cash Page 14 Why Invest In PolyOne? Platform sales and operating income (OI) 2006Y* 2008Y* 2010Y* 2012Y* 2012PF** Global Specialty Engineered Materials Sales $ 345.3 $ 514.0 $ 517.4 $ 543.6 $ 773.0 Global Color, Additives and Inks Sales 531.8 554.3 527.4 703.5 828.5 Designed Structures and Solutions - - - - 850.6 Specialty Platform Sales $ 877.1 $ 1,068.3 $ 1,044.8 $ 1,247.1 $ 2,452.1 Performance Products and Solutions Sales 1,166.2 1,001.4 776.3 837.0 696.1 PolyOne Distribution Sales 732.8 796.7 911.9 1,030.3 1,030.3 Corporate and Eliminations (153.7) (127.7) (111.1) (121.8) (121.6) Total Sales $ 2,622.4 $ 2,738.7 $ 2,621.9 $ 2,992.6 $ 4,056.9 Global Specialty Engineered Materials OI $ 3.9 $ 17.6 $ 49.7 $ 47.0 $ 47.7 Global Color, Additives and Inks OI 8.9 28.1 37.7 66.8 81.6 Designed Structures & Solutions OI - - - - 20.9 Specialty Platform OI $ 12.8 $ 45.7 $ 87.4 $ 113.8 $ 150.2 Performance Products and Solutions OI 64.2 31.3 54.0 74.9 37.4 PolyOne Distribution OI 19.2 28.1 42.0 66.0 66.0 Sunbelt Joint Venture OI 102.9 28.6 18.9 - - Corporate and eliminations (4.6) (28.9) (32.5) (33.7) (40.0) Special items in OI 39.1 (396.2) 4.8 (53.9) (53.9) Operating income (loss) GAAP $ 233.6 $ (291.4) $ 174.6 $ 167.1 $ 159.7 Sunbelt equity income (107.0) (32.5) (23.1) - - Special items in OI (39.1) 396.2 (4.8) 53.9 53.9 Operating income adjusted $ 87.5 $ 72.3 $ 146.7 $ 221.0 $ 213.6 Global Specialty Engineered Materials - OI % of sales 1.1% 3.4% 9.6% 8.6% 6.1% Global Color, Additives and Inks - OI % of sales 1.7% 5.1% 7.1% 9.5% 9.8% Designed Structures & Solutions – OI % of sales - - - - 2.5% Specialty platform OI - % of sales 1.5% 4.3% 8.4% 9.1% 6.1% PP&S operating OI - % of sales 5.5% 3.1% 7.0% 9.0% 5.4% Distribution OI - % of sales 2.6% 3.5% 4.6% 6.4% 6.4% PolyOne OI adjusted - % of sales 3.3% 2.6% 5.6% 7.4% 5.3% * Historical results include the Resin and Specialty Coatings businesses within the Performance Products and Solutions segment. ** Pro Forma results include Spartech and Glasforms acquisitions, Specialty Coatings reclass and exclude the Resin business assets. *** Restated results to exclude the Resin business and to remove Specialty Coatings from the Performance Products and Solutions segment into Global Color, Additives and Inks segment. Average Debt Q2 2012 Q3 2012 Q4 2012 Q1 2013 Q2 2013 Average PolyOne Debt $ 705.8 $ 705.2 $ 706.9 $ 1,055.5 $ 1,031.2 $ 840.9 Average Equity Q2 2012 Q3 2012 Q4 2012 Q1 2013 Q2 2013 Average PolyOne shareholders’ equity $ 604.3 $ 629.3 $ 629.1 $ 871.8 $ 993.9 $ 745.7 Platform sales and operating income (OI) H1 2012*** H1 2013*** H1 2013**** Global Specialty Engineered Materials Sales $ 280.9 $ 352.0 $ 285.1 Global Color, Additives and Inks Sales 413.9 434.7 409.2 Designed Structures & Solutions Sales - 240.4 - Specialty Platform Sales $ 694.8 $ 1,027.1 $694.3 Performance Products and Solutions Sales 336.0 336.7 317.5 PolyOne Distribution Sales 533.6 543.1 543.1 Corporate and Eliminations (62.3) (68.2) (68.2) Total Sales $ 1,502.1 $ 1,838.7 $ 1,486.7 Global Specialty Engineered Materials OI $ 24.6 $ 32.5 $ 31.2 Global Color, Additives and Inks OI 44.0 54.7 52.0 Designed Structures & Solutions OI - 10.5 - Specialty Platform OI $ 68.6 $ 97.7 $ 83.2 Performance Products and Solutions OI 19.3 27.5 25.7 PolyOne Distribution OI 33.4 33.1 33.1 Corporate and eliminations (20.3) (25.7) (20.3) Special items in OI (20.3) (11.4) (20.3) Operating income - GAAP $ 80.7 $ 121.2 $ 101.4 Special items in OI 20.3 11.4 20.3 Operating income adjusted $ 101.0 $ 132.6 $ 121.7 Global Specialty Engineered Materials - OI % of sales 8.8% 9.2% 10.9% Global Color, Additives and Inks - OI % of sales 10.6% 12.6% 12.7% Designed Structures & Solutions - OI % of sales - 4.4% - Specialty platform - OI % of sales 9.9% 9.5% 12.0% PP&S operating - OI % of sales 5.7% 8.2% 8.1% Distribution OI - % of sales 6.3% 6.1% 6.1% PolyOne OI adjusted - % of sales 6.7% 7.2% 8.2% Reconciliation to Condensed Consolidated Balance Sheets H1 2013 Short-term debt and current portion of long-term debt $ 8.7 Long-term debt 1,022.5 Less cash and cash equivalents (392.4) Specialty Platform Gross Margin Percentage 2006Y* Q2 2013**** Global Specialty Engineered Materials Sales $ 345.3 $ 143.5 Global Color, Additives and Inks Sales 531.8 207.5 Specialty Platform Sales $ 877.1 $ 351.0 Global Specialty Engineered Materials Gross Margin $ 41.6 $ 37.3 Global Color, Additives and Inks Gross Margin 83.6 71.8 Specialty Platform Gross Margin $ 125.2 $ 109.1 Specialty Platform Gross Margin Percentage 14.3% 31.1% * Historical results include the Resin and Specialty Coatings businesses within the Performance Products and Solutions segment.

ColorMatrix™ SmartHeat™ RHC ColorMatrix™ SmartHeat™ RHC is a formulated liquid bottle-blowing process aid. It can be supplied as a stand-alone product or as a combination product, where it can be incorporated into a liquid color, acetaldehyde scavenger, or UV light barrier additive. EU FDA Mercosur SmartHeat RHC Yes Yes Yes PACKAGING Package Type Quantity 5G Pail Up to 40 lbs Planetpak Up to 40 lbs Test Description Test Method Units Typical Values Viscosity Avient Method cP 6,000–10,000 Density Avient Method Lbs/gal 7.9–8.9 Color Variance Avient Method ∆E 0.0–1.0 Color Appearance Visual — Slight Blue Dispersion Pressout Visual — Pass Opacity: Visual Visual — Pass TYPICAL GENERAL PROPERTIES1 1Typical values are not to be construed as specifications.

AUTOMOTIVE SOLUTIONS ENGINEERED POLYMERS ELASTOMERS ADVANCED COMPOSITES COLORANTS ADDITIVES PLASTISOLS VINYL POWDERS DESIGN & COLOR SERVICES ENABLING SUSTAINABILITY We are committed to helping you be more sustainable, and our advanced materials aim to support your commitments and meet industry demands. Our global team is here to accelerate development and part approvals, supporting you with: • Materials that meet over 500 automotive polymer OEM specifications • More than 14,000 color and additive approvals for OEM specifications, including more than 2,000 UL94-registered concentrates and pre-colors • Advanced design and color expertise PORTFOLIO HIGHLIGHTS Specialized polymers and composites • Thermoplastic Elastomers • Recycled and Bio-based Thermoplastic Elastomers • Long Fiber Reinforced Formulations • Thermally Conductive Formulations • Static Dissipative, Electrically Conductive, and EMI/RFI Shielding Formulations • Pre-Colored Thermoplastics for Premium Finishes • Engineered Polymer Formulations • Continuous Fiber Tapes & Laminates Colorants, additives, and plastisols • Solid & Liquid Colorants (special effects & bio-based) • Colorant and Additive Concentrates • Functional and Performance Additives (UV, FR, antimicrobial, and more) • Liquid Additives • Chemical Foaming and Nucleating Agents • High-Temperature Concentrates • Silicone Dispersions • Vinyl Powders and Plastisols Design & Color Services • Avient Design • ColorWorks™ Design & Technology Centers UNDERHOOD Air Management Fuel Systems Filters/Cleaners Engines/Power train Fans & Shrouds Engine & Cam Covers Fluid Reservoirs Wire & Cable and Connectors Battery Systems & Supports EV Battery Systems Sensors/Controls/Actuators Turbo/Super Chargers Control Modules/Valves Gears & Hoses HVAC Systems Electrical Control Units EXTERIOR Move over metal... our material and colorant solutions enable you to replace metal and paint while improving miles per gallon or per charge. INTERIOR Our polymers, additives and colorants help you to improve performance, aesthetics, and durability.

products include specialty engineered materials, advanced composites, color and additive systems and polymer distribution. is also a highly specialized developer and manufacturer of performance enhancing additives, liquid colorants and fluoropolymer and silicone colorants.

products include specialty engineered materials, advanced composites, color and additive systems and polymer distribution. is also a highly specialized developer and manufacturer of performance enhancing additives, liquid colorants and fluoropolymer and silicone colorants.

EPS: $1.00 $0.28 $0.36 $0.20 $0.30 $0.40 Q3 '12 Q3 '13 Adjusted EPS $51.8 $72.4 $40.0 $60.0 $80.0 Q3 '12 Q3 '13 Adjusted Operating Income (millions) 40% $31.7 $55.3 $20.0 $40.0 $60.0 Q3 '12 Q3 '13 Specialty Operating Income (millions) Q3 2013 Financial Highlights • Adjusted EPS increased 29% over prior year • Adjusted Operating Income expanded 40% versus Q3 2012 • Specialty operating income up 74% • Revenue increases 43% versus Q3 2012 • Portfolio transformation activities  Completed acquisition of Spartech  Divested non-core Resin Business 29% 74% Page 11 Significant Debt Maturities Other Debt Total Debt at 9/30/13 Less: Cash Net Debt Available Liquidity Cash ABL Availability Total Liquidity Net Debt / EBITDA* = 1.9x $48 $317 $600 $0 $100 $200 $300 $400 $500 $600 $700 $800 2015 2020 2023 Significant Debt Maturities As of September 30, 2013 ($ millions) Page 12 Coupon Rates: 7.500% 7.375% 5.250% Debt Maturities & Liquidity Summary – 9/30/13 $ 965 22 $ 987 323 $ 664 $ 323 308 $631 *TTM 9/30/2013 Cash Balance = $323M Net Debt / EBITDA* = 1.9x • Repurchased 3.8M shares YTD in 2013 • 16.2 million shares are available for repurchase under the current authorization • Repurchased $45 million, par value, of higher coupon bonds YTD Share/Bond Repurchase • Introduced a quarterly dividend in Q1 2011 and increased in Q1 2012 (25%) and Q1 2013 (20%) • Objective of maintaining and growing Dividends • Expanding our sales, marketing, and technical capabilities is top priority • Investing in operational and LSS initiatives (including synergy capture) • North American manufacturing alignment • CAPEX Organic Growth • Targets that expand our: • Specialty offering • End market presence • Geographic footprint • Synergy opportunities • Adjacent material solutions Acquisitions *TTM 9/30/2013 Use of Cash Page 13 Why Invest In PolyOne? Platform sales and operating income (OI) 2006Y* YTD 2013 Organic’ Acquisitions** YTD 2013’ Consolidated Global Specialty Engineered Materials Sales $ 345.3 $ 427.2 $ 113.6 $ 540.8 Global Color, Additives and Inks Sales 531.8 608.0 45.7 653.7 Designed Structures and Solutions Sales - - 428.2 428.2 Specialty Platform Sales $ 877.1 $ 1,035.2 $ 587.5 1,622.7 Performance Products and Solutions Sales 1,166.2 473.6 39.2 512.8 PolyOne Distribution Sales 732.8 818.1 - 818.1 Corporate and eliminations (153.7) (106.0) - (106.0) Total Sales $ 2,622.4 $ 2,220.9 $ 626.7 $ 2,847.6 Global Specialty Engineered Materials OI $ 3.9 $ 46.1 $ 2.1 $ 48.2 Global Color, Additives and Inks OI 8.9 78.0 5.4 83.4 Designed Structures & Solutions OI - - 21.4 21.4 Specialty Platform OI $ 12.8 $ 124.1 $ 28.9 $ 153.0 Performance Products and Solutions OI 64.2 38.1 3.7 41.8 PolyOne Distribution OI 19.2 49.7 - 49.7 Sunbelt Joint Venture OI 102.9 - - - Corporate and eliminations (4.6) (39.5) - (39.5) Special items in OI 39.1 (22.2) - (22.2) Operating income GAAP $ 233.6 $ 150.2 $ 32.6 $ 182.8 Sunbelt equity income (107.0) - - - Special items in OI (39.1) 22.2 - 22.2 Operating income adjusted $ 87.5 $ 172.4 $ 32.6 $ 205.0 Global Specialty Engineered Materials - OI % of sales 1.1% 10.8% 1.8% 8.9% Global Color, Additives and Inks - OI % of sales 1.7% 12.8% 11.8% 12.8% Designed Structures & Solutions - OI % of sales - - 5.0% 5.0% Specialty platform OI - % of sales 1.5% 12.0% 5.0% 9.4% PP&S operating OI - % of sales 5.5% 8.0% 9.4% 8.2% Distribution OI - % of sales 2.6% 6.1% - 6.1% PolyOne OI adjusted - % of sales 3.3% 7.8% 5.2% 7.2% * Historical results include the Resin and Specialty Coatings businesses within the Performance Products and Solutions segment. ** Spartech and Glasforms results for the nine months ended September 30, 2013. Three Months Ended ‘’’’’September 30, Platform operating income “””””””2013 2012 (a) Global Specialty Engineered Materials $ 15.7 $ 13.1 Global Color, Additives and Inks 28.7 18.6 Designed Structures and Solutions 10.9 – Specialty Platform 55.3 31.7 Performance Products and Solutions 14.3 12.3 PolyOne Distribution 16.6 16.4 Corporate and eliminations (24.6) (16.9) Operating income $ 61.6 $ 43.5 (a) Adjusted to reflect the resins business as a discontinued operation.

Melting Point: Melting point is the temperature at which a crystalline polymer becomes a disordered liquid. 4. Using pre-colored resin, where every pellet is precisely the right color 2. Therefore, pre-colored resin is highly recommended