https://www.avient.com/sites/default/files/resources/NOVEL_THERMOPLASTIC_ELASTOMERS_FOR_UNIVERSAL_OVERMOLDING_ON_DISSIMILAR_THERMOPLASTICS.pdf
Figure 1 Surface energy of various thermoplastic elastomers with rigid thermoplastics Engineering Plastics Polyamide 6,6 ABS Polycarbonate Acrylic Polystyrene Polypropylene Polyethylene Elastomers COPA TPU COPE S-TPE TPV mPE Surface Energy (mN/m) 46 43 40 37 34 31 28 Figure 2 Schematic diagram of the peel test Table I Physical property of TPE-1 Shore A Hardness (10 second delay) 44 Specific Gravity (g/cm3) 0.90 Color Natural 300 % Modulus (PSI) 348 Tensile Strength (PSI) 603 Elongation at Break (%) 598 Tear Strength (lbf/in) 110 Table II Adhesion value of TPE-1 on different substrates Substrate Average Peel Strength (lbf) Failure Type PP 17 Cohesive Copolyester 13 Adhesive PET 13 Adhesive PPE/HIPS 18 Adhesive PMMA 15 Adhesive PS 18 Adhesive PC 17 Adhesive PC/ABS 14 Adhesive HIPS 13 Adhesive ABS 13 Adhesive Table III Properties and peel strength of TPE-2 materials 15.37Nylon 11.16.5POM 227Polyester 22.619PC/ABS 24.5-ABS 20.828PP Peel Strength (PIL) 713721Tensile Elongation (%): 10811010Tensile Strength (psi): 5651Hardness: BA 15.37Nylon 11.16.5POM 227Polyester 22.619PC/ABS 24.5-ABS 20.828PP Peel Strength (PIL) 713721Tensile Elongation (%): 10811010Tensile Strength (psi): 5651Hardness: BA Figure 3 Capillary viscosity of TPE-1 and -2 at 200°C 1.00E+00 1.00E+01 1.00E+02 1.00E+03 1.00E+01 1.00E+02 1.00E+03 1.00E+04 1.00E+05 Shear rate (1/sec) Vi sc os ity (P a* se c) TPE-1 TPE-2A TPE-2B GLS Corporation Abstract Introduction Experimental Material Two classes of “universal overmolding TPEs” have been developed and used in this study.
https://www.avient.com/sites/default/files/2024-03/Nymax _ Nymax REC Processing Guide.pdf
Injection Molding Parameters Base Resin PA6 PA6 IM/ST PA6 GF PA6 GMF PA66 IM/ST PA66 GF Barrel Temperatures °F (°C) Rear Zone 450–490 (232–254) 440–490 (226–254) 490–510 (254–265) 480–500 (249–260) 510–530 (265–276) 510–530 (265–276) Center Zone 460–500 (238–260) 450–500 (232–260) 500–520 (260–271) 490–510 (254–265) 510–530 (265–276) 520–540 (271–282) Front Zone 470–510 (243–265) 460–510 (237–265) 510–525 (265–273) 500–520 (260–271) 530–550 (276–288) 530–550 (276–288) Nozzle 480–520 (249–271) 470–510 (243–265) 515–530 (268–276) 510–525 (265–273) 530–560 (276–293) 540–560 (282–293) Melt Temperature °F (°C) 480–520 (249–271) 470–510 (243–265) 515–530 (268–276) 510–525 (265–273) 530–550 (276–288) 540–560 (282–293) Mold Temperature °F (°C) 120–180 (49–82) 120–180 (49–82) 120–200 (49–93) 120–200 (49–93) 140–220 (60–104) 140–220 (60–104) Pack and Hold Pressure 50–80% of Injection Pressure Injection Velocity 1.0–4.0 in/sec Back Pressure 25–100 psi Screw Speed 35–80 rpm Drying Parameters 4 hours @ 180°F (82°C) Moisture Allowable 0.1–0.2% Cushion 0.250 in Screw Compression Ratio 2.0:1–2.5:1 Nozzle Type Reverse Taper Clamp Pressure 3–5 tons/in2 Processing Guide 3 Start Up & Shut Down Recommendations Purge Compound Polypropylene Recycling Recycling prime grades up to 20% is permissible and recycling PIR or PCR grades up to 10% is permissible.
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