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https://www.avient.com/sites/default/files/resources/PolyOne%25202011%2520Annual%2520Report.pdf
Our additive masterbatches encompass a wide variety of performance enhancing characteristics and are commonly categorized by the function that they perform, such as UV stabilization, antimicrobial, anti-static, blowing or foaming, antioxidant, lubricant, and productivity enhancement.
Off-Balance Sheet Arrangements We have no off-balance sheet arrangements as defined in Item 303(a)(4)(ii) of Regulation S-K.
Our additive masterbatches encompass a wide variety of performance enhancing characteristics and are commonly categorized by the function that they perform, such as UV stabilization, anti-static, chemical blowing, antioxidant and lubricant, and processing enhancement.
https://www.avient.com/sites/default/files/2022-11/Smarter Materials High Performance Thermoplastics.pdf
Following are top reasons why many manufacturers and designers choose high-performance thermoplastics: • High-temperature resistance • Chemical resistance • Flame/smoke/toxicity (FST) performance • Chemically inert PLUS, ALL THE BENEFITS OF PLASTIC In addition to their elite-level properties, high-performance thermoplastics deliver the typical advantages of polymers over other material types such as metal, glass and ceramic, including: • Light weight • Design freedom/part consolidation • Easy colorability • Efficient, high-volume processing • Elimination of secondary operations • Enhanced product experience for the end user - quieter environment - improved tactile feel - better usability ADVANTAGES Going Above and Beyond • Amorphous structure • High marks for toughness, chemical resistance, hydrolytic stability, resistance to boiling water, and extreme thermal capabilities • Best for: aerospace interiors, hot water fittings, and medical and dental devices that are subjected to repeated steam sterilization • Also used in food equipment exposed to temperature extremes, such as coffeemakers or freezer-to-microwave cookware Polyaryletherketones Polysulfones Liquid crystal polymers Polyetherimides Polyphenylene sulfides There are five major families of high-performance thermoplastics PO LY AR YL ET H ER KE TO N ES PO LY SU LF O N ES• Semi-crystalline structure • High marks for thermal stability, chemical resistance and mechanical properties over a wide temperature range • Better-than-average levels of combustion resistance and electrical performance • Some PAEK materials, like polyetheretherketone (PEEK), are also extremely tough and have excellent impact strength • Best for: aerospace, automotive, industrial and medical components • May be used to create stock shapes such as rods, bars, and tubes All in the Family PO LY PH EN YL EN E SU LF ID ES • Semi-crystalline structure • Excellent temperature resistance with continuous service temperatures up to 230°C • High marks for modulus and resistance to creep, corrosion, and chemicals • Above-average electrical properties • Best for: complex parts with extremely tight tolerances; often used as an alternative to metals and thermosets in automotive underhood parts, appliances, electronics, and industrial applications Polyaryletherketones Polysulfones Liquid crystal polymers Polyetherimides Polyphenylene sulfides There are five major families of high-performance thermoplastics PO LY ET H ER IM ID ES LI Q U ID C RY ST AL P O LY M ER S • Semi-crystalline structure • High degree of anisotropy: strength, stiffness and thermal expansion will be greater in one direction vs. the other • High marks for temperature, chemical and electrical resistance • Exceptional mechanical strength and high flow rates; often used to fill extremely long parts with thin walls • Best for: electronic connectors, sensors, bullet-resistant vests, jet engine enclosures, brake and transmission friction parts, and gaskets • Amorphous structure • High marks for thermal, mechanical, and chemical properties • Often selected for demanding applications requiring ultra-high mechanical strength combined with high temperature, corrosion and wear resistance • Impact resistance may be lower than that of PSUs and PAEKs • Best for: aerospace interiors, automotive lighting, medical devices, and electrical and fiber optic connectors All in the Family Source: https://www.craftechind.com/standard-and-custom-parts-in-high-performance-plastics/ TEMPERATURE AND MATERIAL TYPE The two broad classifications of high-performance thermoplastics—amorphous and semi-crystalline— have different temperature characteristics.
These can range from viscosity changes that affect consistency of the molding process to dimensional stability and aesthetics of the finished part.
https://www.avient.com/sites/default/files/2020-09/surround-processing-guide-2020.pdf
Furthermore, Surround formulations offer improved performance in the areas of creep and fatigue resistance, dimensional stability, and surface finish when compared to traditional highly-filled, short fiber formulations.
TEMPERATURE Material Rear °F (°C) Center °F (°C) Front °F (°C) Nozzle °F (°C) Melt °F (°C) Mold °F (°C) Nylon 6,6 14% NiCF 540–570 (280–300) 530–560 (275–290) 530–560 (275–290) 540–570 (280–300) 540–570 (280–300) 200–300 (90–150) Nylon 6,6 30% SS 540–570 (280–300) 530–560 (275–290) 530–560 (275–290) 540–570 (280–300) 540–570 (280–300) 200–300 (90–150) PBT 14% NiCF 510–410 (265–280) 490–540 (255–280) 480–530 (250–275) 480–530 (250–275) 480–530 (250–275) 150–250 (65–120) PC 14% NiCF 540–570 (280–300) 540–570 (280–300) 530–560 (275–290) 530–560 (275–290) 530–560 (275–290) 150–250 (65–120) ABS 14% NiCF 470–520 (240–270) 460–520 (240–270) 460–520 (240–270) 460–530 (240–275) 460–530 (240–275) 100–200 (40–90) PP 14% NiCF 440–480 (225–250) 440–480 (225–250) 430–470 (220–245) 420–460 (215–240) 420–460 (215–240) 125–175 (50–80) DRYING Material Temperature °F (°C) Time Minimum Moisture Maximum Moisture Nylon 6,6 14% NiCF 180 (80) 4–5 hours 0.05% 0.20% Nylon 6,6 30% SS 180 (80) 4–5 hours 0.05% 0.20% PBT 14% NiCF 250 (120) 6-8 hours 0.02% 0.03% PC 14% NiCF 250 (120) 3–4 hours 0.02% 0.02% ABS 14% NiCF 200 (90) 2–4 hours 0.05% 0.10% PP 14% NiCF 180 (80) 2–4 hours 0.20% 0.30% Equipment • Feed throats smaller than 2.5" may cause bridging due to pellet size - Larger feed throats will be more advantageous with long fiber EMI shielding resins • General purpose metering screw is recommended - Mixing/barrier screws are not recommended • L/D ratio - 18:1–20:1 (40% feed, 40% transition, 20% metering) • Low compression ratio - 2:1–3:1 • Deep flights recommended - Metering zone 3.5 mm - Feed zone 7.5 mm • Check ring - Three-piece, free-flowing check ring • General purpose nozzle (large nozzle tips are recommended) - Minimum orifice diameter of 7/32" - Tapered nozzles are not recommended for long fiber EMI shielding resins • Clamp tonnage: - 2.5–5 tons/in2 Gates • Large, free-flow gating recommended - 0.25" x 0.125" land length - 0.5" gate depth Runners • Full round gate design • No sharp corners • Minimum of 0.25" diameter • Hot runners can be used PROCESSING Screw Speed Slower screw speeds are recommended to protect fiber length Back Pressure Lower back pressure is recommended to protect fiber length Pack Pressure 60–80% of max injection pressure Hold Pressure 40–60% of max injection pressure Cool Time 10–30 seconds (depends on part geometry and dimensional stability) PROCESS CONSIDERATIONS Recommended – retain fiber length (maximize conductivity) • Low shear process • Low screw speed and screw RPM • Slow Injection speed • Fill to 99–100% on first stage of injection - Reduces potential nesting of fibers at gate location - Improves mechanical performance near gate location - Promotes ideal fiber orientation Resin Rich Surface • Achieved when using a hot mold temperature and longer cure times ≥ Max mold temperature recommendation • Improved surface aesthetic • Reduced surface conductivity • Could reduce attenuation performance in an assembly Fiber Rich Surface • Achieved when using a cold mold temperature and shorter cure times ≤ Minimum mold temperature recommendation • Improved surface aesthetic • Reduced surface conductivity • Could improve attenuation performance in an assembly www.avient.com Copyright © 2020, Avient Corporation.
https://www.avient.com/knowledge-base/article/polymer-services-frequency-asked-questions?rtype[]=1164
Common examples are polypropylene (PP), nylon (PA), polyketone (PK), and thermoplastic elastomers (TPE).
Material Datasets Available
A number of material characterization data sets are available in .udb, moldex 3D, and SIMPOE format.
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