https://www.avient.com/sites/default/files/resources/NOVEL_THERMOPLASTIC_ELASTOMERS_FOR_UNIVERSAL_OVERMOLDING_ON_DISSIMILAR_THERMOPLASTICS.pdf
Rigid thermoplastics include both commodity thermoplastics
and engineering thermoplastics, such as polypropylene (PP), polystyrene (PS), high impact polystyrene
(HIPS), polycarbonate (PC), acrynitrile-butadiene-styrene (ABS), poly(ethylene terephthalate) (PET),
poly(methylmethacrylate) (PMMA), styrene acrylonitrile (SAN), poly(phenylene oxide) (PPO),
polyamide (PA), PC/ABS blend and PPO/PS blend etc..
These TPEs have exhibited good adhesion on various substrates including PP, PS, HIPS,
PMMA, PC, PET, ABS, PC/ABS and Copolyester.
Figure 1
Surface energy of various thermoplastic elastomers with rigid thermoplastics
Engineering
Plastics
Polyamide 6,6
ABS
Polycarbonate
Acrylic
Polystyrene
Polypropylene
Polyethylene
Elastomers
COPA
TPU
COPE
S-TPE
TPV
mPE
Surface
Energy (mN/m)
46
43
40
37
34
31
28
Figure 2
Schematic diagram of the peel test
Table I
Physical property of TPE-1
Shore A Hardness (10 second delay) 44
Specific Gravity (g/cm3) 0.90
Color Natural
300 % Modulus (PSI) 348
Tensile Strength (PSI) 603
Elongation at Break (%) 598
Tear Strength (lbf/in) 110
Table II
Adhesion value of TPE-1 on different substrates
Substrate
Average Peel Strength
(lbf) Failure Type
PP 17 Cohesive
Copolyester 13 Adhesive
PET 13 Adhesive
PPE/HIPS 18 Adhesive
PMMA 15 Adhesive
PS 18 Adhesive
PC 17 Adhesive
PC/ABS 14 Adhesive
HIPS 13 Adhesive
ABS 13 Adhesive
Table III
Properties and peel strength of TPE-2 materials
15.37Nylon
11.16.5POM
227Polyester
22.619PC/ABS
24.5-ABS
20.828PP
Peel Strength (PIL)
713721Tensile Elongation (%):
10811010Tensile Strength (psi):
5651Hardness:
BA
15.37Nylon
11.16.5POM
227Polyester
22.619PC/ABS
24.5-ABS
20.828PP
Peel Strength (PIL)
713721Tensile Elongation (%):
10811010Tensile Strength (psi):
5651Hardness:
BA
Figure 3
Capillary viscosity of TPE-1 and -2 at 200°C
1.00E+00
1.00E+01
1.00E+02
1.00E+03
1.00E+01 1.00E+02 1.00E+03 1.00E+04 1.00E+05
Shear rate (1/sec)
V
is
co
si
ty
(
P
a*
se
c)
TPE-1 TPE-2A TPE-2B
GLS Corporation
Abstract
Introduction
Experimental
Material
Two classes of “universal overmolding TPEs” have been developed and used in this study.
https://www.avient.com/sites/default/files/resources/Novel_Thermoplastic_Elastomers_with_Universal_Bonding_Characteristics.pdf
Rigid thermoplastics include both commodity thermoplastics and
engineering thermoplastics, such as polypropylene (PP), polystyrene (PS), high impact polystyrene (HIPS),
polycarbonate (PC), acrynitrile-butadiene-styrene (ABS), poly(ethylene terephthalate) (PET),
poly(methylmethacrylate) (PMMA), styrene acrylonitrile (SAN), poly(phenylene oxide) (PPO), polyamide
(PA), PC/ABS blend and PPO/PS blend etc..
These TPEs
have exhibited good adhesion on various substrates including PP, PS, HIPS, PMMA, PC, PET, ABS,
PC/ABS and Copolyester.
Adhesion value of TPE-1 on different substrates
TPE-1A TPE-1B
Substrate
Peel Strength
(N/mm) Failure Type
Peel Strength
(N/mm)
Failure Type
PP 3.0 Cohesive 3.7 Cohesive
PS 3.2 Adhesive 2.8 Adhesive
HIPS 2.3 Adhesive 1.9 Adhesive
PPE/HIPS 3.2 Adhesive 3.5 Adhesive
PMMA 2.7 Adhesive 2.7 Adhesive
PC 3.0 Adhesive 2.9 Adhesive
PET 2.3 Adhesive 2.6 Adhesive
Copolyester 2.3 Adhesive 2.8 Adhesive
PC/ABS 2.5 Adhesive 3.1 Adhesive
ABS 2.3 Adhesive 2.6 Adhesive
Table 3.
https://www.avient.com/sites/default/files/2023-12/Cesa Light Additives for Injection Molding Product Bulletin.pdf
BENEFITS
• High additive loading for optimal UV
stabilization
• Solutions available for a large number of
injection molded polymers including PP, PE,
PS, HIPS, ABS, SAN, PA (nylon), PBT, Co-PET, PC,
POM and TPU
• Can be combined with colors and other
additives in Smartbatch™ solutions
• Formulations can be customized to meet
specific regulatory compliance, e.g., EU and US
food contact, toy, UL 94 recognition
PRODUCT BULLETIN
Copyright © 2023, Avient Corporation.
https://www.avient.com/sites/default/files/2024-06/Cesa Flame Retardant Product Selection Guide %281%29.pdf
POLYMER PRODUCT NAME PROPERTY PERFORMANCE TYPE DOSAGE/LDR
MATERIAL
CODE
ABS FRABS92991 UL 94 Halogen 35% CC10292991WE
ABS FRABS52399 UL 94 Halogen 5–14% CC10252399WE
HDPE Cesa Flam MB 5101AH UL 94 Halogen 7–16% PEAN698479
Nylon Cesa Flam MB 5728H UL 94 Halogen 8–14% ABA0698450
Nylon Cesa Flam MB 5731NH UL 94 Non-halogen 8–20% ABAN698410
PC Cesa Flam NCA0820018NH UL 94 Non-halogen 2–4% NCA0820018
PC NCAN-Z0N-FN FLMRET 698419 UL 94 Non-halogen 3–8% NCAN698419
PE FRPE94802 ASTM E84 Non-halogen 100% CC103094802F
PE FRPE41011 UL 94 Halogen 20–30% CC1034101160
PET Cesa Flam MB 5525NH UL 1441, UL 94 Non-halogen 6–8% NEAN698534
PET FRPET65462 UL 94 Non-halogen 5–12% CC103265462F
PET/ PBT Cesa Flam MB 5532NH NFPA 701 Non-halogen 4–6% NBAN698451
PP Cesa Flam MB 5201H UL 94 Halogen 6–30% PPAN698410
PP Cesa Flam MB CT-1629NH Cal TB 133, UL 94 Film, NFPA 701 Non-halogen 6–8% PPAN698428
PP FRPP365370 UL 94 Non-halogen 10–20% CC103653702F
PP Copolymer FRPP37654 UL 94 5VA Halogen 100% CC10337654WE
PP Copolymer FRPP53484 UL 94 Halogen 10% CC1035348460
PS FRPS62722 ASTM E84 Halogen 2–4% CC10262722WE
PS/HIPS Cesa Flam SLA0820014H UL 94 Halogen 4–8% SLA0820014H
TPU Cesa Flam 98461NH UL 94 Non-halogen 6–14% RUA0698461
F-SERIES FLAME RETARDANT ADDITIVES
HDPE/PE F-Series UL 94 Non-halogen 10–25% PEA0820024
PE F-Series UL 2335, FM 4998 Non-halogen 10–25% PEA0820069
https://www.avient.com/resources/safety-data-sheets?page=5626
DENIM HIPS
WHITE HIPS
ZAFIRO HIPS
https://www.avient.com/sites/default/files/2023-09/Color _ Additive Masterbatches for E_E Application Bulletin_A4.pdf
OnColor™ UL 94 Colorants*
• More than 2,000 recognized concentrates
available worldwide in all color options
• HB rating for most of PP, PS, ABS, PC/ABS, PBT,
PA, PA-GF, TPU generic resins
• V-0, V-1, V-2 and 5VA/5VB ratings for more than
200 specific engineering resins
• Master file of recognized concentrates with
scope of use accessible in the UL product finder
• Development of custom products for specific
resins upon request
• Compliance Letters available for REACH and
RoHS
Cesa™ Flame Retardant Additives
for Glow Wire
• Fire performance in line with different levels of
Glow Wire temperatures (IEC 60695-2-12)
• Let-Down Ratio adjustable to reach different
levels of Glow Wire temperatures
• Non-halogen (in accordance with IEC 61249-
2-21) and non-HBCD** solutions
• Wide range of solutions adapted to different
polymers (PP, PS, PC)
• Color and flame retardants can be combined
in one product
• Compliance Letters available for REACH
and RoHS
APPLICATION BULLETIN
* Solutions also sold as Renol™ UL 94 Colorants
APPLICATION
POLYMER
GWFI
TEMPERATURE
TYPICAL
LET-DOWN RATIO CONTENT
HIPS 750–960°C 5–10%
Non-HBCD
flame retardant**
PC 850–960°C 2–4%
Non-halogen in accordance
with IEC 61249-2-21
PP homopolymer 850–960°C 4%
Non-halogen in accordance
with IEC 61249-2-21
PP copolymer 850–960°C 4–8%
Antioxidant - metal
deactivator
** Non-HBCD means that Hexabromocyclododecane (HBCD) is neither used as starting material during the mixing phase of our products nor
intentionally added during production, but it cannot be excluded that it is not present at level of ubiquitous traces in any of the raw materials
used in manufacturing of our products.
https://www.avient.com/resources/safety-data-sheets?page=6653
WHITE HIPS
HIPS DARK GRAY-F
HIPS ORANGE-F
https://www.avient.com/resources/safety-data-sheets?page=7144
HIPS ORANGE
HIPS PINK
HIPS BLUE
https://www.avient.com/resources/safety-data-sheets?page=6034
SNOW WHITE HIPS
BISQUE HIPS
DORIAN GRAY HIPS
https://www.avient.com/resources/safety-data-sheets?page=5689
HIPS WHITE
DSS WHITE HIPS
DSS BLACK HIPS