 Addressable market exceeds $40 billion  Strong performance demonstrates that our strategy and execution are working  Megatrends and emerging opportunities align with our strengths  Innovation and services provide differentiation, incremental pricing power, and competitive advantage  Strong and proven management team driving growth and performance PolyOne Corporation Page 22 Appendix PolyOne Corporation Page 23 $0.24 $0.31 $0.44 $0.46 $0.56 $0.00 $0.25 $0.50 $0.75 1Q'12 1Q'13 1Q'14 1Q'15 1Q'16 Adjusted EPS 1Q 2016 Financial Highlights  Performance Products & Solutions operating margin grew 540 basis points year-over-year to 11.9%  Distribution operating margin expanded 60 basis points to a record first quarter level of 6.5%  First quarter adjusted EPS has grown on average 24% per year since 2012 $11 $0 $5 $10 $15 $25 1Q'15 1Q'16 PP&S Operating Profit $16 $18 $10 $12 $14 $16 $18 1Q'15 1Q'16 POD Operating Profit Note: $ in millions, except per share data PolyOne Corporation Page 24 1.7% 4.6% 5.1% 5.5% 7.2% 8.1% 12.2% 16.7% 17.0% Color, Additives and Inks 2015 Revenues: $0.8 Billion Solutions Expanding Profits2015 Revenue by Industry Segment 48% 33% Building & Electrical & 1% 31% Textiles PolyOne Corporation Page 25 1.1% 1.3% 3.4% 5.1% 9.6% 8.0% 8.6% 9.3% 16.6% Specialty Engineered Materials 2015 Revenues: $0.5 Billion Solutions 2015 Revenue by Industry Segment Expanding Profits 12.1% 49% 29% Building & Electrical & 19% 15% PolyOne Corporation Page 26 1.4% 5.6% 7.3% 3.0% 8-10% 0.4% 2012 2013 2014 2015 1Q'16 2020 Designed Structures and Solutions Solutions2015 Revenues: $0.5 Billion Expanding Profits2015 Revenue by Industry Segment Appliances, Building & Construction Industrial 24% Packaging 19% Transportation 33% 97% PolyOne Corporation Page 27 Building & 31% Electrical & 1% 5% Transportation 19% Wire & Cable 5.5% 6.9% 3.8% 3.6% 5.5% 4.3% 6.3% 7.2% 8.3% 12-14% Performance Products and Solutions Solutions Expanding Profits 2015 Revenues: $0.7 Billion 11.9% 2015 Revenue by Industry Segment 7.7% 79% PolyOne Corporation Page 28 2.6% 3.0% 3.5% 4.0% 4.6% 5.6% 6.4% 5.9% 6.6% 6.5-7.5% 6.5% 15% 54% 2006 1Q 2016 Distribution Key Suppliers2015 Revenues: $1.0 Billion ROIC Expanding Profits 6.1% Building & 4%Consumer Electrical & 23% 24% http://www.polyone.com/Pages/VariationRoot.aspx http://www.polyone.com/Pages/VariationRoot.aspx PolyOne Corporation Page 29 2 lbs Plastic = 3 lbs aluminum or 8 lbs steel or 27 lbs glass 33% less material by weight than aluminum 75% less material by weight than steel 93% less material by weight than glass Requires 91% less energy to recycle a pound of plastic versus a pound of paper Source: SPI: Sustainability and the Plastics Industry Plastics: Key to Future Sustainable Development PolyOne Corporation Page 30 Application Examples PolyOne Corporation Page 31 Outdoor Applications • Leading provider of high performance specialty materials for the recreational and sports & leisure industry • Well positioned across all segments to address market needs  Metal to Polymer Conversion  Lightweighting  Thermal Management  Impact Performance Source: Outdoor Industry Association PolyOne Corporation Page 32  $1.5 billion attractive, growing market  Additives improve performance and reduce cost through light-weighting, reduced waste, faster cycle times, and extended shelf life of finished product  Aligned with megatrend of protecting the environment:  Sustainability benefits include lower package weight and improved recyclability of package at end of use Market Opportunity Leading Global Supplier of Additives In Growing PET Market Shelf-life extension Greater product consistency Recyclability and reduced carbon footprint Color and Special Effects Weight reduction Enhanced product aesthetics High heat resistance PET Bottling Technology 0.0 10.0 20.0 30.0 40.0 50.0 60.0 70.0 2009 2014 2019 Asia Pacific North America Latin America Western Europe Eastern Europe Middle East and Africa Global PET Packaging Growth 2009-2019 Source: Euromonitor retail off-trade consumption (PET bottles & jars, home care, personal care, food & non-alcoholic beverages) B ill io n un its 5% CAGR PolyOne Corporation Page 33 • Includes formulation and consultative services to assist manufacturers and brand owners in positively identifying their finished goods • Protects brand equity & consumer welfare • Reduces exposure to unwarranted recall expenses • Secures supply chain integrity – support for safe expansion into new geographies Authentication Technology PolyOne Corporation Page 34 Metal Replacement Solutions • Replaces metal in LED lighting • Extends LED durability and life span eliminating hot spots • Greater design flexibility with fewer parts • Weight reduction • Simplifies manufacturing and lowers total production cost PolyOne Corporation Page 35 • Color harmonization across 15 unique color-and-polymer combinations • Eliminated need for multiple pre- colored materials • Reduced Land Rover’s working capital Range Rover Evoque Interior PolyOne Corporation Page 36 • Reduced health and environmental impact • System cost reduction • Radiation-shielding performance • Parts consolidation • Design freedom CT Scanner PolyOne Corporation Page 37 High-Barrier Packaging Containers • Capability to extrude up to 13 layers • Strong oxygen and moisture vapor transmission protection • Can be made symmetrical or asymmetrical to meet customized needs of broad variety of applications • Barrier protection and superior sensory properties PolyOne Corporation Page 38 Aerospace Applications • Leading provider of specialty materials for the aerospace industry • Typical applications  Mil-spec aircraft windows, canopies, windscreens, instrument panels, wingtip lenses  Interior – gallery furnishings, tray tables, arm rests, trim strips, joint/edge coverings • Benefits:  High impact strength  Resistant to UV rays  Flame and smoke compliance  Easy to clean with aggressive cleaners; anti-microbial grades available  Range of sizes, thicknesses, colors, etc. 1 Reconciliation of Non-GAAP Financial Measures (Unaudited) (Dollars in millions, except per share data) Below is a reconciliation of non-GAAP financial measures to the most directly comparable measures calculated and presented in accordance with U.S. Appendix 1Q 2016 Financial Highlights At a Glance�Color, Additives and Inks At a Glance�Specialty Engineered Materials At a Glance�Designed Structures and Solutions At a Glance�Performance Products and Solutions At a Glance�Distribution Plastics: Key to Future Sustainable Development Application Examples Outdoor Applications Slide Number 32 Authentication Technology Metal Replacement Solutions Range Rover Evoque Interior Slide Number 36 High-Barrier Packaging Containers Aerospace Applications Investor Presentation - May 17, 2016 r7 Investor Presentation - May 17, 2016

Equipment Benefi t Scanning Electron Microscopy with Energy Dispersive X-ray System Capability to look at material and property defects at the most detailed level with magnifi cation up to 800,000x Digital Optical Microscope Ability to non-destructively capture fully-focused images with a depth-of-fi eld 20x larger than conventional microscopes Microwave Sample Digestion System Aids in sample preparation for heavy metal analysis Mechanical Spectrometer Estimates how a medical device will structurally perform when subjected to the load within a human body Differential Scanning Calorimeter Analyzes the transition temperatures of materials and also determines the purity of the materials to predict likelihood of defects Chromatography Accessories Facilitates compositional analysis of materials and devices as well as the ability to analyze extractables Copyright © 2011, Polymer Diagnostics Inc. Equipment Benefi t Scanning Electron Microscopy with Energy Dispersive X-ray System Capability to look at material and property defects at the most detailed level with magnifi cation up to 800,000x Digital Optical Microscope Ability to non-destructively capture fully-focused images with a depth-of-fi eld 20x larger than conventional microscopes Microwave Sample Digestion System Aids in sample preparation for heavy metal analysis Mechanical Spectrometer Estimates how a medical device will structurally perform when subjected to the load within a human body Differential Scanning Calorimeter Analyzes the transition temperatures of materials and also determines the purity of the materials to predict likelihood of defects Chromatography Accessories Facilitates compositional analysis of materials and devices as well as the ability to analyze extractables Copyright © 2011, Polymer Diagnostics Inc.

Plastic or metal reels are also available.

COLORANTS & ADDITIVES FOR HEALTHCARE Essential polymer solutions for critical healthcare applications WHEN MATERIAL EXPERTISE IS CRITICAL AESTHETIC APPEAL Regulatory compliant and approved masterbatch colors use custom polymer colorants to achieve any shade SPECIAL EFFECTS Enhance your brand and stand apart with pearlescent, metallic, iridescent, fluorescent or thermo-chromatic effects SOLID TO LIQUID SOLUTIONS Choose from a full range of available color solutions, from liquid color to solid product forms ANTIMICROBIALS Efficacy performance and regulatory requirements are met in a wide range of resins compatible with Withstand™ antimicrobial technology SURFACE ENERGY MODIFICATION Additive technologies such as low retention, hydrophobic, lubricious, light diffusion, or anti-stat provide desired surface manipulation Materials used for today’s medical devices, parts and pharmaceutical packaging contribute significantly to performance and, in turn, to a patient’s health and well-being.

This pure metal replacement solution can be customized to meet specific density requirements, formulated to meet a broad modulus range, and engineered to meet complex design specifications.

OnColor™ UL 94 Colorants* • More than 2,000 recognized concentrates available worldwide in all color options • HB rating for most of PP, PS, ABS, PC/ABS, PBT, PA, PA-GF, TPU generic resins • V-0, V-1, V-2 and 5VA/5VB ratings for more than 200 specific engineering resins • Master file of recognized concentrates with scope of use accessible in the UL product finder • Development of custom products for specific resins upon request • Compliance Letters available for REACH and RoHS Cesa™ Flame Retardant Additives for Glow Wire • Fire performance in line with different levels of Glow Wire temperatures (IEC 60695-2-12) • Let-Down Ratio adjustable to reach different levels of Glow Wire temperatures • Non-halogen (in accordance with IEC 61249- 2-21) and non-HBCD** solutions • Wide range of solutions adapted to different polymers (PP, PS, PC) • Color and flame retardants can be combined in one product • Compliance Letters available for REACH and RoHS APPLICATION BULLETIN * Solutions also sold as Renol™ UL 94 Colorants APPLICATION POLYMER GWFI TEMPERATURE TYPICAL LET-DOWN RATIO CONTENT HIPS 750–960°C 5–10% Non-HBCD flame retardant** PC 850–960°C 2–4% Non-halogen in accordance with IEC 61249-2-21 PP homopolymer 850–960°C 4% Non-halogen in accordance with IEC 61249-2-21 PP copolymer 850–960°C 4–8% Antioxidant - metal deactivator ** Non-HBCD means that Hexabromocyclododecane (HBCD) is neither used as starting material during the mixing phase of our products nor intentionally added during production, but it cannot be excluded that it is not present at level of ubiquitous traces in any of the raw materials used in manufacturing of our products.

Formulations are heavy metal-free and manufactured using state-of-the- art pigment dispersion techniques that improve homogenization and color distribution.

Synthetically, antimony trioxide is made by roasting antimony metal in a furnace with oxygen present.

This extensive range of products includes Reflective, Pearlescent, Metallics, Brittle and Suede to bring prints to life.

A LOOK INTO THE FUTURE VIRTUAL REALITY APPLICATION BULLETIN AESTHETIC APPEAL Metallic and Custom Effects, FDA-Approved Masterbatch Colorants SOLUTION: Custom Polymer Colorants, Pre-Colored Resins WEARABLE COMFORT Flexibility, Skin- Compatible Comfort, Soft Touch, Heat Reduction SOLUTION: Thermoplastic Elastomers (TPEs), Thermoplastic Urethanes (TPUs), Silicone, Nylon (PA) FUNCTIONALITY Impact Resistance, Dimensional Stability, Strength SOLUTION: Copolyester, PC/ Polyester Blends, Polycarbonate, Styrenics BETTER EXPERIENCES.