S&P 500 All time high of $42.47 June 6th, 2014 PolyOne Corporation Page 9 2006 Q1 2014 2015 “Where we were” “Where we are” Target 1) Operating Income % Specialty: Global Color, Additives & Inks 1.7% 13.8% 12 – 16% Global Specialty Engineered Materials 1.1% 11.6% 12 – 16% Designed Structures & Solutions -- 6.5% 8 – 10% Performance Products & Solutions 5.5% 7.7% 9 – 12% Distribution 2.6% 6.1% 6 – 7.5% 2) Specialty Platform % of Operating Income 6.0% 64% 65 – 75% 3) ROIC* 5.0% 9.4% 15% 4) Adjusted EPS Growth N/A 42% Double Digit Expansion Proof of Performance & 2015 Goals *ROIC is defined as TTM adjusted OI divided by the sum of average debt and equity over a 5 quarter period PolyOne Corporation Page 10 Bridge to $2.50 Adjusted EPS by 2015 2015 EPS: $2.50 2013 EPS: $1.31 Continued Gross Margin Expansion Mergers & Acquisitions Spartech Accretion Incremental Share Buybacks Ongoing LSS Programs (50-100 bps/yr) Accelerated Innovation & Mix Improvement Several Levers to Drive Growth Mid Single Digit Revenue CAGR PolyOne Corporation Page 11 Innovation Drives Earnings Growth *Percentage of Specialty Platform revenue from products introduced in last five years $20 $53 2006 2013 Research & Development Spending ($ millions) Specialty Platform Vitality Index Progression* 14.3% 30.7% 2006 2013 Specialty Platform Gross Margin % 19.5% 43.0% 2006 2013 Specialty Vitality Index Target ≥ 35% PolyOne Corporation Page 12 Healthcare Consumer Packaging and Additive Technology Transportation Unique and Innovative Solutions https://www.dropbox.com/sh/dwe4t8aacvhb8ui/uD3p_bdglP/Presentation revise pics/GLS Beverage can closure XO 2.jpg https://www.dropbox.com/sh/dwe4t8aacvhb8ui/-YgkycKypw/Anti-Counterfeiting release & images/GN1979.JPG PolyOne Corporation Page 13 Megatrends Aligned with Key End Markets Decreasing Dependence on Fossil Fuels Protecting the Environment Improving Health and Wellness Megatrend End Markets Globalizing and Localizing Health & Wellness Transportation Packaging Consumer PolyOne Corporation Page 14 60% 100% 20% 30% 40% 50% 60% 70% 80% 90% 100% 2008 2014 Pension Funding** As of March 31, 2014 Debt Maturities & Pension Funding – 3/31/14 Net Debt / EBITDA* = 1.9x $48 $317 $600 $0 $100 $200 $300 $400 $500 $600 $700 $800 2015 2020 2023 Debt Maturities As of March 31, 2014 ($ millions) Coupon Rates: 7.500% 7.375% 5.250% ** includes US-qualified pension plans only *TTM 3/31/2014 PolyOne Corporation Page 15 Free Cash Flow and Strong Balance Sheet Fund Investment / Shareholder Return $0.16 $0.20 $0.24 $0.32 $0.10 $0.20 $0.30 $0.40 2011 2012 2013 2014 Annual Dividend Expanding our sales, marketing, and technical capabilities Targets that expand our: • Specialty offerings • End market presence • Geographic footprint • Operating Margin Synergy opportunities Adjacent material solutions Repurchased 1.4 million shares in Q1 2014 Repurchased 6.4 million shares since April 2013  13.6 million shares are available for repurchase under the current authorization Organic Growth Acquisitions Share Repurchases Dividends  Investing in operational and LSS initiatives (including synergy capture) Manufacturing alignment PolyOne Corporation Page 16 Formula for Success Innovation Market Beating Performance Excellence in Execution PolyOne Corporation Page 17 The New PolyOne: A Specialty Growth Company Why Invest In PolyOne? Platform operating income mix percentage 2005Y* 2008Y* 2010Y* 2013Y 2014 Q1 Global Specialty Engineered Materials $ 0.4 $ 17.6 $ 49.7 $ 57.2 $ 18.3 Global Color, Additives and Inks 4.3 28.1 37.7 104.0 30.4 Designed Structures and Solutions - - - 33.4 11.2 Specialty Platform $ 4.7 $ 45.7 $ 87.4 $ 194.6 $ 59.9 Performance Products and Solutions 75.7 31.3 54.0 56.0 16.0 Distribution 19.5 28.1 42.0 63.3 17.2 SunBelt Joint venture 91.9 28.6 18.9 - - Corporate (51.5) (425.1) (27.7) (82.4) (36.7) Operating income (loss) GAAP $ 140.3 $ (291.4) $ 174.6 $ 231.5 $ 56.4 Less: Corporate operating expense 51.5 425.1 27.7 82.4 36.7 Operating income excluding Corporate $ 191.8 $ 133.7 $ 202.3 $ 313.9 $ 93.1 Specialty platform operating mix percentage 2% 34% 43% 62% 64% * Historical results include the Resin and Specialty Coatings businesses within the Performance Products and Solutions segment.

S&P 500 All time high of $39.55 May 13th, 2014 Page 8 2006 Q1 2014 2015 “Where we were” “Where we are” Target 1) Operating Income % Specialty: Global Color, Additives & Inks 1.7% 13.8% 12 – 16% Global Specialty Engineered Materials 1.1% 11.6% 12 – 16% Designed Structures & Solutions -- 6.5% 8 – 10% Performance Products & Solutions 5.5% 7.7% 9 – 12% Distribution 2.6% 6.1% 6 – 7.5% 2) Specialty Platform % of Operating Income 6.0% 64% 65 – 75% 3) ROIC* 5.0% 9.4% 15% 4) Adjusted EPS Growth N/A 42% Double Digit Expansion Proof of Performance & 2015 Goals *ROIC is defined as TTM adjusted OI divided by the sum of average debt and equity over a 5 quarter period Page 9 Bridge to $2.50 Adjusted EPS by 2015 2015 EPS: $2.50 2013 EPS: $1.31 Continued Gross Margin Expansion Mergers & Acquisitions Spartech Accretion Incremental share buybacks Ongoing LSS Programs (50-100 bps/yr) Accelerated Innovation & Mix Improvement Several Levers to Drive Growth Mid single digit revenue CAGR Page 10 Innovation Drives Earnings Growth *Percentage of Specialty Platform revenue from products introduced in last five years Page 11 $20 $53 2006 2013 Research & Development Spending ($ millions) Specialty Platform Vitality Index Progression* 14.3% 30.7% 2006 2013 Specialty Platform Gross Margin % 19.5% 43.0% 2006 2013 Healthcare Consumer Packaging and Additive Technology Transportation Page 12 Unique and Innovative Solutions https://www.dropbox.com/sh/dwe4t8aacvhb8ui/uD3p_bdglP/Presentation revise pics/GLS Beverage can closure XO 2.jpg https://www.dropbox.com/sh/dwe4t8aacvhb8ui/-YgkycKypw/Anti-Counterfeiting release & images/GN1979.JPG 60% 100% 20% 30% 40% 50% 60% 70% 80% 90% 100% 2008 2014 Pension Funding** As of March 31, 2014 Debt Maturities & Pension Funding – 3/31/14 Net Debt / EBITDA* = 1.9x $48 $317 $600 $0 $100 $200 $300 $400 $500 $600 $700 $800 2015 2020 2023 Debt Maturities As of March 31, 2014 ($ millions) Coupon Rates: 7.500% 7.375% 5.250% ** includes US-qualified pension plans only *TTM 3/31/2014 Page 13 Free Cash Flow and Strong Balance Sheet Fund Investment / Shareholder Return $0.16 $0.20 $0.24 $0.32 $0.10 $0.20 $0.30 $0.40 2011 2012 2013 2014 Annual Dividend  Expanding our sales, marketing, and technical capabilities  Targets that expand our: • Specialty offerings • End market presence • Geographic footprint • Operating Margin  Synergy opportunities  Adjacent material solutions  Repurchased 1.4 million shares in Q1 2014  Repurchased 6.4 million shares since April 2013  13.6 million shares are available for repurchase under the current authorization Organic Growth Acquisitions Share Repurchases Dividends  Investing in operational and LSS initiatives (including synergy capture) Manufacturing alignment Page 14 The New PolyOne: A Specialty Growth Company Why Invest In PolyOne? Platform operating income mix percentage 2005Y* 2008Y* 2010Y* 2013Y 2014 Q1 Global Specialty Engineered Materials $ 0.4 $ 17.6 $ 49.7 $ 57.2 $ 18.3 Global Color, Additives and Inks 4.3 28.1 37.7 104.0 30.4 Designed Structures and Solutions - - - 33.4 11.2 Specialty Platform $ 4.7 $ 45.7 $ 87.4 $ 194.6 $ 59.9 Performance Products and Solutions 75.7 31.3 54.0 56.0 16.0 Distribution 19.5 28.1 42.0 63.3 17.2 SunBelt Joint venture 91.9 28.6 18.9 - - Corporate (51.5) (425.1) (27.7) (82.4) (36.7) Operating income (loss) GAAP $ 140.3 $ (291.4) $ 174.6 $ 231.5 $ 56.4 Less: Corporate operating expense 51.5 425.1 27.7 82.4 36.7 Operating income excluding Corporate $ 191.8 $ 133.7 $ 202.3 $ 313.9 $ 93.1 Specialty platform operating mix percentage 2% 34% 43% 62% 64% * Historical results include the Resin and Specialty Coatings businesses within the Performance Products and Solutions segment.

Certain things cannot be controlled by the printer: • The dye in the shirt • The humidity in the air and shirt Things that can be controlled are: • The type of ink – cotton white for cotton, non-ghosting bleed resistant for polyester • The amount of heat used on the garment—cure at the recommended temp, not over • Stack in separate piles to allow cooling—fold in dozens separately, wait to pack Be aware of at-risk colors; brown, tan and beige are the most sensitive to possible ghosting.

APPLICATION BULLETIN DIMENSIONAL STABILITY Tight tolerances, minimal warp SOLUTION: Long fiber reinforced composites with polyketone (PK) POSSIBILITIES: Roof rack structures, running boards, brackets, component housings STRENGTH High strength- to-weight ratio, comparable to metal SOLUTION: Long fiber POSSIBILITIES: Tubular door frames, accessory motor mounts, tailgate locking systems MANUFACTURING EASE Injection moldable, design freedom, insert molding, part consolidation SOLUTION: Long fiber reinforced composites POSSIBILITIES: Seating shells, seat base components, tubular door frames, accessory linkages IMPACT RESISTANCE Durable in rugged environments and uses SOLUTION: Maximum toughness long fiber POSSIBILITIES: Side steps, bed steps, roof racks, brackets, bed extenders, tie downs CORROSION RESISTANCE Metal replacement, eliminate secondary coatings SOLUTION: Long fiber POSSIBILITIES: Underbody skid plate components, fuel doors, fasteners SUSTAINABILITY PIR/PCR content incorporation with high strength, lightweighting for fuel economy SOLUTION: Recycled content long fiber reinforced composites POSSIBILITIES: Roof rack structures, fender flares, rail covers, tail light protectors LIGHTWEIGHTING 30–40% weight reduction when switching from metal SOLUTION: Long carbon fiber reinforced composites POSSIBILITIES: Motor mounts, seating components, accessory mounts EXTREME PERFORMANCE High and low temperature performance, maintained properties with UV exposure, moisture performance SOLUTION: Long fiber POSSIBILITIES: Tail light protectors, fender flairs, guards, underbody components SURFACE AESTHETICS Color matches, fiber-rich or glossy surfaces, carbon fiber appearance SOLUTION: Moisture-resistant long fiber reinforced composites POSSIBILITIES: Lighting bars, side steps, bed steps, bike mounting brackets, cargo carriers NEXT-GEN UPGRADES Transform your aftermarket parts with efficient, lightweight long fiber thermoplastic solutions that redefine performance with strength, toughness, and design freedom.

KEY CHARACTERISTICS Avient CRTM panels offer significant benefits to customers, including: • Superior strength to weight ratio • �Unlimited length capability; widths up to 108" • �Thermal insulation • Ultra-low thermal conductivity • �Customized density, thickness, weight and color • �Vibration damping and acoustic insulation • Chemical and corrosion resistance • Consistent cross-sections and quality PRODUCT BULLETIN Other thicknesses/architectures are available.

They can be filled and reinforced to satisfy required performance characteristics and can be blended with glass, minerals, impact modifiers, colorants and stabilizer systems.

WithStand antimicrobial additives can be combined with colorants or other functional additives in a single masterbatch or liquid solution to get the exact performance needed.

Avient can provide support and assistance on every aspect of liquid color and additive processing.

PC PUMP RATE (cc/rev) 0.09 0.28 0.87 2.6 5.2 RECOMMENDED OUTPUT RANGE (g/min) 0.9–9 2.8–28 8.7–87 26–260 53–520 MAX PUMP OUTPUT (g/min) 18 56 174 520 1040 Avient can provide support and assistance on every aspect of liquid color and additive processing.

ONFLEX™ LO 7120-45 ONFLEX™ HT 40A-3S2131 BERGAFLEX™ BFIG 45A-300 Applications HVAC Seals HVAC Seals HVAC Seals Interior - direct airflow Interior & exterior Interior - direct airflow HVAC feature Low VOC/FOG & odor Low VOC/FOG & odor Low odor Cold air Hot air Cold air VDA 270 ≤3.0 ≤3.0 ≤3.0 VOC/FOG VDA 278 (VOC) 97µg/g 100µg/g 196µg/g VDA 278 (FOG) 1131µg/g 1116µg/g 1707µg/g DIN 75201 (FOG) 0.3mg 1.7mg 1.1mg 73°F (23°C) 72 hrs 15% 12% 15% 158°F (70°C) 22 hrs 45% 28% 50% 212°F (100°C) 22 hrs 70% 45% 90% Density 1.15 g/ml 1.00 g/ml 1.17 g/ml Processing Injection Molding Injection Molding/ Extrusion Injection Molding Bonds to Polypropylene Polypropylene/ Polyethylene Polypropylene Hardness range 35–65 Shore A 40–70 Shore A 35–65 Shore A HOW GLS TPEs MAKE THE DIFFERENCE IN AUTOMOTIVE HVAC APPLICATIONS • Low VOC/FOG – externally tested to VDA 278 and shows significant reductions in volatile organic compounds and fogging when compared to current TPE technologies • Industry standards – helps to achieve VOC/ FOG performance standards for improved VIAQ • Reduced manufacturing steps – does not require pre-drying or post heating to reduce VOC in parts produced • Design optimization – color can be added at the machine • Easy to process – can be extruded, injection molded and extrusion blow molded • Recyclable – Our automotive TPEs are compatible with most municipal recycle streams • Global support – Avient automotive TPEs can be manufactured in locations that are convenient to your operations, including North America, Europe or China To learn more about GLS TPEs for automotive applications, contact Avient at +1.844.4AVIENT (+1.844.428.4368).